Spatial correlations of elementary relaxation events in glass-forming liquids

被引:19
作者
Pastore, Raffaele [1 ]
Coniglio, Antonio [2 ]
Ciamarra, Massimo Pica [1 ,3 ]
机构
[1] CNR, SPIN, Sez Napoli, I-00185 Rome, Italy
[2] Ist Nazl Fis Nucl, Sez Napoli, I-80126 Naples, Italy
[3] Nanyang Technol Univ, Div Phys & Appl Phys, Sch Phys & Math Sci, Singapore 639798, Singapore
关键词
FOAM MECHANICS; DYNAMICS; MODEL; TRANSITION; SCALE; JUMPS;
D O I
10.1039/c5sm01510c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dynamical facilitation scenario, by which localized relaxation events promote nearby relaxation events in an avalanche process, has been suggested as the key mechanism connecting the microscopic and the macroscopic dynamics of structural glasses. Here we investigate the statistical features of this process via numerical simulations of a model structural glass. First we show that the relaxation dynamics of the system occurs through particle jumps that are irreversible, and that cannot be decomposed in smaller irreversible events. Then we show that each jump does actually trigger an avalanche. The characteristics of this avalanche change upon cooling, suggesting that the relaxation dynamics crossovers from a noise dominated regime, where jumps do not trigger other relaxation events, to a regime dominated by the facilitation process, where a jump triggers more relaxation events.
引用
收藏
页码:7214 / 7218
页数:5
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