The influence of the addition of tungsten trioxide nanoparticle size on structure, thermal, and electroactivity properties of hybrid material-reinforced PANI

被引：27

作者：

Belardja, M. S. ^{[1
]}

Djelad, H. ^{[1
]}

Lafjah, M. ^{[2
]}

Chouli, F. ^{[3
]}

Benyoucef, Abdelghani ^{[1
]}

机构：

[1] Univ Mustapha Stambouli Mascara, LSTE Lab, Mascara, Algeria

[2] Univ Oran 1 Ahmed Ben Bella, Fac Sci Exactes & Appliquees, Lab Chim Mat, Oran, Algeria

[3] Univ Mustapha Stambouli Mascara, Fac Sci & Technol, Mascara, Algeria

来源：

COLLOID AND POLYMER SCIENCE | 2020年 / 298卷 / 11期

关键词：

Polyaniline; Tungsten trioxide; Hybrid materials; Optical properties; Electrochemical test; POLYANILINE; NANOCOMPOSITES; COMPOSITE; ZNO; WO3; POLYMERIZATION; NANOFIBERS; ELECTRODE; SURFACE; SENSOR;

D O I：

10.1007/s00396-020-04720-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanomaterials are synthetized by aniline with different contents of WO(3)nanoparticles using a chemical oxidative polymerization method. FTIR, ultraviolet-visible, XPS, SEM, and XRD confirmed the successful synthesis of the three PANI@WO(3)samples. Thermogravimetric analysis shows an improved thermal stability by the presence of WO(3)in nanocomposites compared with PANI. Interestingly, the analysis of the band gap shows lowest value of optical band gap of 1.88 eV for PANI@WO3(0.5) compared with PANI@WO3(1.0) and PANI@WO3(1.5) with 1.91 eV and 1.98 eV, respectively. In addition, the electroactivity properties were investigated by cyclic voltammetry to explore the benefits of these types of hybrid materials in electrochemical applications.

引用

页码：1455 / 1463

页数：9

共 40 条

[1] Asim N., 2014, PROCEDIA SOC BEHAV S, V9, P175, DOI DOI 10.1016/J.APCBEE.2014.01.031
[2] Porous orthorhombic tungsten oxide thin films: synthesis, characterization, and application in electrochromic and photochromic devices
Balaji, Subramanian
Djaoued, Yahia
Albert, Andre-Sebastien
Bruening, Ralf
Beaudoin, Normand
Robichaud, Jacques
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (11) : 3940 - 3948
[3] Nanoparticules Mass Effect of ZnO on the Properties of Poly(4-Chloroaniline)/Zinc Oxide Nanocomposites
Bekhoukh, A.
Zehhaf, A.
Benyoucef, Abdelghani
Bousalem, S.
Belbachir, M.
[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2017, 27 (01) : 13 - 20
[4] Development of novel hybrid materials based on poly(2-aminophenyl disulfide)/silica gel: Preparation, characterization and electrochemical studies
Benyakhou, S.
Belmokhtar, A.
Zehhaf, A.
Benyoucef, A.
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2017, 1150 : 580 - 585
[5] PANI-derived polymer/Al2O3 nanocomposites: synthesis, characterization, and electrochemical studies
Benykhlef, S.
Bekhoukh, A.
Berenguer, R.
Benyoucef, A.
Morallon, E.
[J]. COLLOID AND POLYMER SCIENCE, 2016, 294 (12) : 1877 - 1885
[6] Physical and electrochemical investigations on hybrid materials synthesized by polyaniline with various amounts of ZnO nanoparticle
Bousalem, S.
Zeggai, F. Z.
Baltach, H.
Benyoucef, A.
[J]. CHEMICAL PHYSICS LETTERS, 2020, 741
[7] A novel conducting nanocomposite obtained by p-anisidine and aniline with titanium(IV) oxide nanoparticles: Synthesis, Characterization, and Electrochemical properties
Chouli, F.
Radja, I.
Morallon, E.
Benyoucef, A.
[J]. POLYMER COMPOSITES, 2017, 38 : E254 - E260
[8] Chemical polymerization, characterization and electrochemical studies of PANI/ZnO doped with hydrochloric acid and/or zinc chloride: Differences between the synthesized nanocomposites
Daikh, S.
Zeggai, F. Z.
Bellil, A.
Benyoucef, A.
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2018, 121 : 78 - 84
[9] Polyaniline/MnO2/porous carbon nanofiber electrodes for supercapacitors
Dirican, Mahmut
Yanilmaz, Meltem
Asiri, Abdullah M.
Zhang, Xiangwu
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2020, 861
[10] Ac and Dc conductivities of polyaniline/poly vinyl formal blend films
Ebrahim, Shaker
Kashyout, Abdel-Hady
Soliman, Moataz
[J]. CURRENT APPLIED PHYSICS, 2009, 9 (02) : 448 - 454

← 1 2 3 4 →