The viscoelastic properties of bulk Zr55Cu25Ni5Al10Nb5 metallic glass

被引:21
作者
Wang, Q
Pelletier, JM
Xia, L
Xu, H
Dong, YD
机构
[1] Inst Natl Sci Appl, GEMPPM, F-69621 Villeurbanne, France
[2] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai 200030, Peoples R China
[3] Shanghai Univ, Inst Mat, Shanghai 200072, Peoples R China
关键词
bulk metallic glass; viscoelasticity; relaxation; fragility index;
D O I
10.1016/j.jallcom.2005.02.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we have investigated the dynamic shear modulus of the bulk Zr55Cu25Ni5Al10Nb5 metallic glasses over large temperature and frequency ranges. Like in other conventional glass forming systems. a distinct alpha relaxation with typical kinetic features is experimentally detected. Therefore, the fragility parameter, m, which is estimated from the activation energy for viscoelastic deformation, indicates that the Zr base bulk amorphous alloy is a relatively strong liquid. On the other hand. during the main mechanical relaxation, the frequency dependence of dynamic shear modulus of the Zr base bulk amorphous alloy follows the biparabolic equation derived from a physical model, which can characterize the atomic mobility and mechanical response of disordered condensed materials. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:181 / 187
页数:7
相关论文
共 39 条
[1]   ON TEMPERATURE DEPENDENCE OF COOPERATIVE RELAXATION PROPERTIES IN GLASS-FORMING LIQUIDS [J].
ADAM, G ;
GIBBS, JH .
JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (01) :139-&
[2]   SPECIFIC-HEAT SPECTROSCOPY OF THE GLASS-TRANSITION [J].
BIRGE, NO ;
NAGEL, SR .
PHYSICAL REVIEW LETTERS, 1985, 54 (25) :2674-2677
[3]   Comparative internal friction study of bulk and ribbon glassy Zr52.5Ti5CU17.9Ni14.6Al10 [J].
Bobrov, OP ;
Khonik, VA ;
Laptev, SN ;
Yazvitsky, MY .
SCRIPTA MATERIALIA, 2003, 49 (03) :255-260
[4]   NONEXPONENTIAL RELAXATIONS IN STRONG AND FRAGILE GLASS FORMERS [J].
BOHMER, R ;
NGAI, KL ;
ANGELL, CA ;
PLAZEK, DJ .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) :4201-4209
[5]   Viscosity of the supercooled liquid and relaxation at the glass transition of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass forming alloy [J].
Busch, R ;
Bakke, E ;
Johnson, WL .
ACTA MATERIALIA, 1998, 46 (13) :4725-4732
[6]   The kinetic glass transition of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass former-supercooled liquids on a long time scale [J].
Busch, R ;
Johnson, WL .
APPLIED PHYSICS LETTERS, 1998, 72 (21) :2695-2697
[7]   MOLECULAR THEORY FOR THE RHEOLOGY OF GLASSES AND POLYMERS [J].
CAVAILLE, JY ;
PEREZ, J ;
JOHARI, GP .
PHYSICAL REVIEW B, 1989, 39 (04) :2411-2422
[8]   A COMPARISON OF A POINT-DEFECTS THEORY WITH MECHANICAL RELAXATIONS IN POLYMERS [J].
CAVAILLE, JY ;
PEREZ, J ;
JOHARI, GP .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 131 :935-941
[9]   MOLECULAR TRANSPORT IN LIQUIDS AND GLASSES [J].
COHEN, MH ;
TURNBULL, D .
JOURNAL OF CHEMICAL PHYSICS, 1959, 31 (05) :1164-1169
[10]   Supercooled liquids and the glass transition [J].
Debenedetti, PG ;
Stillinger, FH .
NATURE, 2001, 410 (6825) :259-267