Iron production from Fe3O4 and graphite by applying 915 MHz microwaves

被引:30
作者
Kashimura, Keiichiro [1 ]
Sato, Motoyasu [2 ]
Hotta, Masahiro [3 ]
Agrawal, Dinesh Kumar [4 ]
Nagata, Kazuhiro [5 ]
Hayashi, Miyuki [3 ]
Mitani, Tomohiko [1 ]
Shinohara, Naoki [1 ]
机构
[1] Kyoto Univ, Uji, Kyoto 6110011, Japan
[2] Natl Inst Nat Sci, Natl Inst Fus Sci, Toki, Gifu 5095292, Japan
[3] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528552, Japan
[4] Penn State Univ, Mat Res Inst, Microwave Proc & Engn Ctr, University Pk, PA 16802 USA
[5] Tokyo Univ Arts, Dept Conservat Sci, Taito Ku, Tokyo 1108714, Japan
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2012年 / 556卷
关键词
Microwave heating; Metal oxides; 915; MHz; Microwave chemistry; Wustite; HIGH-TEMPERATURE; REDUCTION;
D O I
10.1016/j.msea.2012.07.049
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The chemical behavior of iron ore reduction was experimentally studied under electric and magnetic fields of microwaves. The microwave magnetic field rapidly heated the powdery ores so that the reduction of the ore to metal ions was completed. The mechanism was investigated theoretically. It was found that the combined effect of thermal energy and a portion of the microwave magnetic field enhanced deoxidation and that the microwaves act as a dynamic catalyst at high temperatures. High-frequency magnetic fields were found to enhance the antibonding character of oxygen in materials with unpaired spins above the Fermi level of the 3d shell. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:977 / 979
页数:3
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