Single-Photon and Two-Photon Induced Photocleavage for Monolayers of an Alkyltriethoxysilane with a Photoprotected Carboxylic Ester

被引:58
作者
Alvarez, Marta [1 ,2 ]
Best, Andreas [2 ]
Pradhan-Kadam, Swapna [2 ]
Koynov, Kaloian [2 ]
Jonas, Ulrich
Kreiter, Maximilian [2 ]
机构
[1] FORTH IESL, Iraklion 71110, Greece
[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
D O I
10.1002/adma.200800746
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photochemical structuring of a polysiloxane monolayer protected with a photocleavable group is shown by femtosecond laser pulses in the near-infrared. These experiments suggest a two-photon induced deprotection process that holds great promise for near-field monolayer photolithography far below the diffraction limit.
引用
收藏
页码:4563 / 4567
页数:5
相关论文
共 24 条
[1]   Imaging the irradiance distribution in the optical near field [J].
Aizenberg, J ;
Rogers, JA ;
Paul, KE ;
Whitesides, GM .
APPLIED PHYSICS LETTERS, 1997, 71 (26) :3773-3775
[2]   Photolabile protecting groups and linkers [J].
Bochet, CG .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (02) :125-142
[3]   Novel labile protected amine terpolymers for the preparation of patterned functionalized surfaces: Synthesis and characterization [J].
Braun, F ;
Eng, L ;
Trogisch, S ;
Voit, B .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (12) :1486-1496
[4]   Surface modification with orthogonal photosensitive silanes for sequential chemical lithography and site-selective particle deposition [J].
del Campo, A ;
Boos, D ;
Spiess, HW ;
Jonas, U .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4707-4712
[5]   DEEP UV PHOTOCHEMISTRY OF CHEMISORBED MONOLAYERS - PATTERNED COPLANAR MOLECULAR ASSEMBLIES [J].
DULCEY, CS ;
GEORGER, JH ;
KRAUTHAMER, V ;
STENGER, DA ;
FARE, TL ;
CALVERT, JM .
SCIENCE, 1991, 252 (5005) :551-554
[6]   Functionalisation of Si/SiO2 and glass surfaces with ultrathin dextran films and deposition of lipid bilayers [J].
Elender, G ;
Kuhner, M ;
Sackmann, E .
BIOSENSORS & BIOELECTRONICS, 1996, 11 (6-7) :565-577
[7]   LIGHT-DIRECTED, SPATIALLY ADDRESSABLE PARALLEL CHEMICAL SYNTHESIS [J].
FODOR, SPA ;
READ, JL ;
PIRRUNG, MC ;
STRYER, L ;
LU, AT ;
SOLAS, D .
SCIENCE, 1991, 251 (4995) :767-773
[8]  
Goppert-Mayer M, 1931, ANN PHYS-BERLIN, V9, P273
[9]   Photodimerized 7-hydroxycoumarin with improved solubility in PMMA:: Single-photon and two-photon-induced photocleavage in solution and PMMA films [J].
Haertner, Sebastian ;
Kim, Hee-Cheol ;
Hampp, Norbert .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 187 (2-3) :242-246
[10]   Three-dimensional nanofabrication with rubber stamps and conformable photomasks [J].
Jeon, S ;
Menard, E ;
Park, JU ;
Maria, J ;
Meitl, M ;
Zaumseil, J ;
Rogers, JA .
ADVANCED MATERIALS, 2004, 16 (15) :1369-1373