STEM plasmon spectroscopy of free standing graphene

被引:19
作者
Bangert, U. [1 ]
Eberlein, T. [2 ]
Nair, R. R. [1 ,4 ]
Jones, R. [2 ]
Gass, M. [3 ]
Bleloch, A. L. [3 ]
Novoselov, K. S. [4 ]
Geim, A. [4 ]
Briddon, P. R. [5 ]
机构
[1] Univ Manchester, Sch Mat, Manchester M1 7HS, Lancs, England
[2] Univ Exeter, Sch Phys, Exeter EX4 4QL, Devon, England
[3] CCLRC Daresbury Lab, SuperSTEM Labs, Warrington WA4 4AD, Cheshire, England
[4] Univ Manchester, Sch Phys & Astron, Manchester M1 7HS, Lancs, England
[5] Newcastle Univ, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2008年 / 205卷 / 09期
关键词
D O I
10.1002/pssa.200879707
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Plasmon spectroscopy of the thinnest possible membrane, a single layer of carbon atoms, graphene, has been carried out in conjunction with ab initio calculations of the low loss function. We observe pi- and pi+ sigma-surface plasmon modes in free-standing single sheets at 4.7 eV and 14.8 eV which are substantially red-shifted from their values in graphite. These modes are in very good agreement with the theoretical spectra which find the pi- and pi + pi in-plane modes of graphene at 4.5 eV and 14.5 eV. We also find that there is little loss caused by out-of-plane modes for energies less than about 10 eV. (C) 2008 WILEY-NCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2265 / 2269
页数:5
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