Palladium catalysts for cross-coupling of ortho-substituted aryl triflates with Grignard reagents

被引:0
作者
Kamikawa, T [1 ]
Hayashi, T [1 ]
机构
[1] KYOTO UNIV,FAC SCI,DEPT CHEM,SAKYO KU,KYOTO 60601,JAPAN
关键词
cross-coupling; Grignard reagent; aryl triflate; palladium catalyst;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dichloro [(2-dimethylamino)propyldiphenylphosphine]palladium (PdCl2(alaphos)) and dichloro[1,3-bis(diphenylphosphino)-propane]palladium (PdCl2(dppp)) were found to be much more effective catalysts than PdCl2(PPh(3))(2) and other palladium complexes for cross-coupling of sterically congested aryl triflates with aryl and alkynyl Grignard reagents.
引用
收藏
页码:163 / &
页数:3
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