C3N4-sensitized TiO2 nanotube arrays with enhanced visible-light photoelectrochemical performance

被引:36
作者
Yang, Manman [1 ]
Liu, Juan [1 ]
Zhang, Xing [1 ]
Qiao, Shi [1 ]
Huang, Hui [1 ]
Liu, Yang [1 ]
Kang, Zhenhui [1 ]
机构
[1] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
PHOTOCATALYTIC ACTIVITY; COMPOSITE PHOTOCATALYST; HYDROGEN GENERATION; CARBON NITRIDES; NANOWIRE ARRAYS; WATER; G-C3N4/TIO2; HYBRID; TITANIUM; NANOSTRUCTURES;
D O I
10.1039/c5cp01580d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A C3N4-sensitized TiO2 nanotube array-based photoanode was designed and fabricated via the in situ growth of C3N4 on the surface of TiO2 nanotubes. It shows stable and significantly improved PEC activity for hydrogen generation under visible light irradiation with a hydrogen production rate of about 19.1 mu mol h(-1) (a Faradaic efficiency of nearly 100%).
引用
收藏
页码:17887 / 17893
页数:7
相关论文
共 62 条
[1]   Synthesis of Carbon Nanotube-Anatase TiO2 Sub-micrometer-sized Sphere Composite Photocatalyst for Synergistic Degradation of Gaseous Styrene [J].
An, Taicheng ;
Chen, Jiangyao ;
Nie, Xin ;
Li, Guiying ;
Zhang, Haimin ;
Liu, Xiaolu ;
Zhao, Huijun .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (11) :5988-5996
[2]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[3]   Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects [J].
Bak, T ;
Nowotny, J ;
Rekas, M ;
Sorrell, CC .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (10) :991-1022
[4]   Solar Cells by Design: Photoelectrochemistry of TiO2 Nanorod Arrays Decorated with CdSe [J].
Bang, Jin Ho ;
Kamat, Prashant V. .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (12) :1970-1976
[5]   Enhanced visible-light photocatalytic activity of g-C3N4/TiO2 films [J].
Boonprakob, Natkritta ;
Wetchakun, Natda ;
Phanichphant, Sukon ;
Waxler, David ;
Sherrell, Peter ;
Nattestad, Andrew ;
Chen, Jun ;
Inceesungvorn, Burapat .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 417 :402-409
[6]   g-C3N4-Based Photocatalysts for Hydrogen Generation [J].
Cao, Shaowen ;
Yu, Jiaguo .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (12) :2101-2107
[7]   Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals [J].
Chen, Xiaobo ;
Liu, Lei ;
Yu, Peter Y. ;
Mao, Samuel S. .
SCIENCE, 2011, 331 (6018) :746-750
[8]   Construction of Heterostructured g-C3N4/Ag/TiO2 Microspheres with Enhanced Photocatalysis Performance under Visible-Light Irradiation [J].
Chen, Yanfeng ;
Huang, Weixin ;
He, Donglin ;
Yue Situ ;
Huang, Hong .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (16) :14405-14414
[9]   Branched TiO2 Nanorods for Photoelectrochemical Hydrogen Production [J].
Cho, In Sun ;
Chen, Zhebo ;
Forman, Arnold J. ;
Kim, Dong Rip ;
Rao, Pratap M. ;
Jaramillo, Thomas F. ;
Zheng, Xiaolin .
NANO LETTERS, 2011, 11 (11) :4978-4984
[10]   Metal-free activation of H2O2 by g-C3N4 under visible light irradiation for the degradation of organic pollutants [J].
Cui, Yanjuan ;
Ding, Zhengxin ;
Liu, Ping ;
Antonietti, Markus ;
Fu, Xianzhi ;
Wang, Xinchen .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (04) :1455-1462