Boosted spatial charge carrier separation of binary ZnFe2O4/S-g-C3N4 heterojunction for visible-light-driven photocatalytic activity and antimicrobial performance

被引:10
作者
Iqbal, Shahid [1 ]
Amjad, Adnan [2 ,3 ]
Javed, Mohsin [3 ]
Alfakeer, M. [4 ]
Mushtaq, Muhammad [2 ]
Rabea, Sameh [5 ]
Elkaeed, Eslam B. [5 ]
Pashameah, Rami Adel [6 ]
Alzahrani, Eman [7 ]
Farouk, Abd-ElAziem [8 ]
机构
[1] Natl Univ Sci & Technol NUST, Dept Chem, Sch Nat Sci SNS, Islamabad, Pakistan
[2] Govt Coll Univ, Dept Chem, Lahore, Pakistan
[3] Univ Management & Technol, Sch Sci, Dept Chem, Lahore, Pakistan
[4] Princess Nourah Bint Abdulrahman Univ, Dept Chem, Coll Sci, Riyadh, Saudi Arabia
[5] AlMaarefa Univ, Dept Pharmaceut Sci, Coll Pharm, Riyadh, Saudi Arabia
[6] Umm Al Qura Univ, Fac Appl Sci, Dept Chem, Mecca, Saudi Arabia
[7] Taif Univ, Dept Chem, Coll Sci, Taif, Saudi Arabia
[8] Taif Univ, Coll Sci, Dept Biotechnol, Taif, Saudi Arabia
关键词
binary heterojunction; synergic effects; photocatalysis; spatial charge separation; antimicrobial activity; GRAPHITIC CARBON NITRIDE; ZINC FERRITE NANOPARTICLES; ELECTRONIC-STRUCTURE; FACILE SYNTHESIS; H-2; EVOLUTION; CO2; REDUCTION; DOPED G-C3N4; DEGRADATION; SULFUR; NANOCOMPOSITES;
D O I
10.3389/fchem.2022.975355
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A potential method for removing toxins from contaminated wastewater, especially organic pollutants, is photo-catalysis. Here, a simple technique for producing zinc ferrite nanoparticles (ZnFe2O4 NPS) with varying quantities of sulphur doped graphitic carbon nitride nanocomposites (ZnFe2O4/S-g-C3N4 NCs) has been described. Then, using X-ray diffraction (XRD), TEM, EDX, XPS, photocurrent response, EIS, and Fourier Transform Infrared spectroscopy (FTIR), the photo-catalytic activity of the produced nanoparticles (NPs) and nanocomposites (NCs) was examined and evaluated. The photo-catalytic activity of ZnFe2O4/S-g-C3N4 NCs was compared to a model pollutant dye, methylene blue, while degradation was evaluated spectrophotometrically (MB). Solar light has been used through irradiation as a source of lighting. The photocatalytic behaviour of the ZnFe2O4/S-g-C3N4 NCs photocatalyst was superior to that of genuine ZnFe2O4 and S-g-C3N4, which was attributed to synergic effects at the ZnFe2O4/S-g-C3N4 interconnection. Antimicrobial activity of ZnFe2O4/S-g-C3N4 against Gram-positive and Gram-negative bacteria under visible light was performed. In addition, these ZnFe2O4/S-g-C3N4 NCs show a lot of promise as an antibacterial agent.
引用
收藏
页数:12
相关论文
共 61 条
[1]   Ternary magnetic g-C3N4/Fe3O4/AgI nanocomposites: Novel recyclable photocatalysts with enhanced activity in degradation of different pollutants under visible light [J].
Akhundi, Anise ;
Habibi-Yangieh, Aziz .
MATERIALS CHEMISTRY AND PHYSICS, 2016, 174 :59-69
[2]   Advances in water treatment by adsorption technology [J].
Ali, Imran ;
Gupta, V. K. .
NATURE PROTOCOLS, 2006, 1 (06) :2661-2667
[3]   Enhanced photodegradation of methylene blue with alkaline and transition-metal ferrite nanophotocatalysts under direct sun light irradiation [J].
Ali, Nauman ;
Zada, Amir ;
Zahid, Muhammad ;
Ismail, Ahmed ;
Rafiq, Misbha ;
Riaz, Aaisha ;
Khan, Adnan .
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2019, 66 (04) :402-408
[4]   Chitosan-coated cotton cloth supported copper nanoparticles for toxic dye reduction [J].
Ali, Nauman ;
Awais ;
Kamal, Tahseen ;
Ul-Islam, Mazhar ;
Khan, Adnan ;
Shah, Syed Jamal ;
Zada, Amir .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2018, 111 :832-838
[5]   Simultaneous removal of chromium(VI) and fluoride by electrocoagulation-electroflotation: Application of a hybrid Fe-Al anode [J].
Aoudj, S. ;
Khelifa, A. ;
Drouiche, N. ;
Belkada, R. ;
Miroud, D. .
CHEMICAL ENGINEERING JOURNAL, 2015, 267 :153-162
[6]   Magnetization of sol-gel prepared zinc ferrite nanoparticles: Effects of inversion and particle size [J].
Atif, M. ;
Hasanain, S. K. ;
Nadeem, M. .
SOLID STATE COMMUNICATIONS, 2006, 138 (08) :416-421
[7]   Schiff based ligand containing nano-composite adsorbent for optical copper(II) ions removal from aqueous solutions [J].
Awual, Md Rabiul ;
Eldesoky, Gaber E. ;
Yaita, Tsuyoshi ;
Naushad, Mu ;
Shiwaku, Hideaki ;
AlOthman, Zeid A. ;
Suzuki, Shinichi .
CHEMICAL ENGINEERING JOURNAL, 2015, 279 :639-647
[8]   Synergistic ZnFe2O4-carbon allotropes nanocomposite photocatalyst for norfloxacin degradation and Cr (VI) reduction [J].
Behera, Arjun ;
Mansingh, Sriram ;
Das, Kundan Kumar ;
Parida, Kulamani .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 544 :96-111
[9]   Facile and reliable route for synthesis of zinc ferrite nanoparticles and its application in photo-degradation of methyl orange [J].
Biglari, Narges ;
Nasiri, Abbas ;
Pakdel, Sina ;
Nasiri, Mahdi .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (12) :13113-13118
[10]   Enhancement of visible-light-driven photocatalytic H2 evolution from water over g-C3N4 through combination with perylene diimide aggregates [J].
Chen, Shuai ;
Wang, Chen ;
Bunes, Benjamin R. ;
Li, Yingxuan ;
Wang, Chuanyi ;
Zang, Ling .
APPLIED CATALYSIS A-GENERAL, 2015, 498 :63-68