Direct catalytic asymmetric aldol reactions of aldehydes with unmodified ketones

被引：361

作者：

Yamada, YMA ^{[1
]}

Yoshikawa, N ^{[1
]}

Sasai, H ^{[1
]}

Shibasaki, M ^{[1
]}

机构：

[1] UNIV TOKYO, GRAD SCH PHARMACEUT SCI, BUNKYO KU, TOKYO 113, JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1997年 / 36卷 / 17期

关键词：

aldol reactions; asymmetric catalysis; asymmetric synthesis; homogeneous catalysis; lanthanum;

D O I：

10.1002/anie.199718711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：1871 / 1873

页数：3

共 31 条

[1] Self-assembly of heterobimetallic complexes and reactive nucleophiles: A general strategy for the activation of asymmetric reactions promoted by heterobimetallic catalysts [J].

Arai, T ;

Yamada, YMA ;

Yamamoto, N ;

Sasai, H ;

Shibasaki, M .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (11) :1368-1372

[2] LANTHANIDE SHIFT REAGENTS FOR NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

COCKERILL, AF ;

DAVIES, GLO ;

HARDEN, RC ;

RACKHAM, DM .

CHEMICAL REVIEWS, 1973, 73 (06) :553-588

[3] ENANTIOSELECTIVE MUKAIYAMA-ALDOL AND ALDOL-DIHYDROPYRONE ANNULATION REACTIONS CATALYZED BY A TRYPTOPHAN-DERIVED OXAZABOROLIDINE [J].

COREY, EJ ;

CYWIN, CL ;

ROPER, TD .

TETRAHEDRON LETTERS, 1992, 33 (46) :6907-6910

[4] NUCLEAR MAGNETIC-RESONANCE ENANTIOMER REAGENTS - CONFIGURATIONAL CORRELATIONS VIA NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS OF DIASTEREOMERIC MANDELATE, O-METHYLMANDELATE, AND ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETATE (MTPA) ESTERS [J].

DALE, JA ;

MOSHER, HS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) :512-519

[5] Chemistry of trichlorosilyl enolates .1. New reagents for catalytic, asymmetric aldol additions [J].

Denmark, SE ;

Winter, SBD ;

Su, XP ;

Wong, KT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (31) :7404-7405

[6] C-2-symmetric copper(II) complexes as chiral Lewis acids. Catalytic enantioselective aldol additions of silylketene acetals to (benzyloxy)acetaldehyde [J].

Evans, DA ;

Murry, JA ;

Kozlowski, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5814-5815

[7]

Fessner W.-D., 1996, Angew. Chem, V108, P2366

[8] The mechanism of class II, metal-dependent aldolases [J].

Fessner, WD ;

Schneider, A ;

Held, H ;

Sinerius, G ;

Walter, C ;

Hixon, M ;

Schloss, JV .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (19) :2219-2221

[9] CATALYTIC ASYMMETRIC ALDOL REACTIONS - USE OF A CHIRAL (ACYLOXY)BORANE COMPLEX AS A VERSATILE LEWIS ACID CATALYST [J].

FURUTA, K ;

MARUYAMA, T ;

YAMAMOTO, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1041-1042

[10] PRONOUNCED SOLVENT AND CONCENTRATION EFFECTS IN AN ENANTIOSELECTIVE MUKAIYAMA ALDOL CONDENSATION USING BINOL-TITANIUM(IV) CATALYSTS [J].

KECK, GE ;

KRISHNAMURTHY, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (08) :2363-2364

← 1 2 3 4 →