Multielectron-Transfer Templates via Consecutive Two-Electron Transformations: Iron-Sulfur Complexes Relevant to Biological Enzymes

被引：35

作者：

Chen, Lin ^{[1
]}

Wang, Mei ^{[1
]}

Gloaguen, Frederic ^{[2
]}

Zheng, Dehua ^{[1
]}

Zhang, Peili ^{[1
]}

Sun, Licheng ^{[1
,3
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, Dalian 116024, Peoples R China

[2] Univ Bretagne Occidentale, UMR 6521, CNRS, CS 93837, F-29238 Brest, France

[3] Royal Inst Technol KTH, Dept Chem, Stockholm, Sweden

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 44期

基金：

瑞典研究理事会;

关键词：

electrochemistry; electron transfer; hydrogenase; iron complexes; FE-FE HYDROGENASE; X-RAY STRUCTURES; ELECTRON-TRANSFER; PROTON REDUCTION; CARBONYL; ANALOGS; LIGANDS; ACIDS;

D O I：

10.1002/chem.201201326

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[FeFe] hydrogenase mimics: Two polynuclear iron-sulfur complexes (1 and 2; see figure) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13968 / 13973

页数：6

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