Tailoring polyvinyl alcohol with triazinanes and formaldehyde

被引：18

作者：

Gungor, Fusun Seyma ^{[1
]}

Kiskan, Baris ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2018年 / 124卷

关键词：

Polyvinyl alcohol; Thermosetting; Triazinane; Formaldehyde; Gels; POLY(VINYL ALCOHOL); ACETALIZATION; HYDROLYSIS; BLENDS; GELS;

D O I：

10.1016/j.reactfunctpolym.2018.01.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cross-linking of polyvinyl alcohol (PVA) was achieved by using functional 1,3,5-triazinanes and formaldehyde as cross-linking agents. This method can be considered as an alternative to acetalization of PVA by monoaldehydes. The gels obtained with the triazinane method exhibited dimensional stability and resistance against acids. Control experiments were performed to have a better insight of the gelation process. The products of control experiments and obtained gels were characterized spectroscopically by FTIR and H-1 NMR and thermally by DSC. Moreover, swelling in water and acid stability of gels were investigated and compared to the PVA-formaldehyde system.

引用

页码：115 / 120

页数：6

共 44 条

[1]

AMANO M, 1987, POLYM COMMUN, V28, P119

[2] Synthesis and properties of organo-gels by thiol-benzoxazine chemistry [J].

Bektas, Semiha ;

Kiskan, Baris ;

Orakdogen, Nermin ;

Yagci, Yusuf .

POLYMER, 2015, 75 :44-50

[3] Preparation of poly(vinyl formyl) of high acetalization [J].

Chetri, P ;

Dass, NN .

POLYMER, 1997, 38 (15) :3951-3956

[4] Poly(vinyl alcohol) Functionalization with Aldehydes in Organic Solvents: Shining Properties of Poly(vinyl acetals) [J].

Delattre, Emilie ;

Lemiere, Gilles ;

Desmurs, Jean-Roger ;

Boulay, Benjamin ;

Dunach, Elisabet .

JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (17) :8482-8490

[5] Thermally curable fluorinated main chain benzoxazine polyethers via Ullmann coupling [J].

Demir, Kubra Dogan ;

Kiskan, Baris ;

Latthe, Sanjay S. ;

Demirel, A. Levent ;

Yagci, Yusuf .

POLYMER CHEMISTRY, 2013, 4 (06) :2106-2114

[6]

Dolce T. J., 2002, ENCY POLYM SCI TECHN

[7] Synthesis of poly(vinyl butyral)s in homogeneous phase and their thermal properties [J].

Fernandez, M. D. ;

Fernandez, M. J. ;

Hoces, P. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (05) :5007-5017

[8] Investigation on the thermal properties of new thermo-reversible networks based on poly(vinyl furfural) and multifunctional maleimide compounds [J].

Gaina, C. ;

Ursache, O. ;

Gaina, V. ;

Buruiana, E. ;

Ionita, D. .

EXPRESS POLYMER LETTERS, 2012, 6 (02) :129-141

[9] Acetalization of polyvinyl alcohol with furfural [J].

Gousse, C ;

Gandini, A .

EUROPEAN POLYMER JOURNAL, 1997, 33 (05) :667-671

[10] Investigation of Factors Affecting Synthesis of Polyvinyl Butyral by Taguchi Method [J].

Hajian, Morteza ;

Koohmareh, Gholam Ali ;

Rastgoo, Mahdi .

JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 115 (06) :3592-3597

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