Microstructured Al/Fe2O3/Nitrocellulose Energetic Fibers Realized by Electrospinning

被引:41
作者
Li, Rui [1 ,2 ]
Xu, Hongmei [3 ]
Hu, Hailong [3 ]
Yang, Guangcheng [1 ,2 ]
Wang, Jun [2 ]
Shen, Jinpeng [1 ,2 ]
机构
[1] Sichuan Res Ctr New Mat, Mianyang 621000, Peoples R China
[2] China Acad Engn Phys, Inst Chem Mat, Mianyang, Peoples R China
[3] Southwest Univ Sci & Technol, Mianyang, Peoples R China
基金
中国国家自然科学基金;
关键词
mechanical property; metastable intermolecular composites; microfibers; thermal analysis; COMBUSTION BEHAVIOR; ALUMINUM NANOPOWDERS; NANOFIBERS; THERMITES; NITROCELLULOSE; IGNITION; NANO; NANOSTRUCTURES; DIAMETER;
D O I
10.1080/07370652.2012.754515
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
At present, metastable intermolecular composites (MICs) have been widely studied for their potential in high-density energetic materials and nanotechnology, but the relatively low-pressure discharge in a short period of time and the oxidation of Al powders have seriously impeded their applications in rocket solid fuels and explosives. In this work, the authors successfully fabricated microstructured Al/Fe2O3/nitrocellulose (Al/Fe2O3/NC) fibers via simple electrospinning, introducing nitrocellulose (NC), a gas generator to MICs. In view of previous reports, wrapping nAl in NC fibers might reduce their further oxidation during storage. In addition, the thermal properties and elastic modulus of NC fibers were measured before and after adding Al/Fe2O3.
引用
收藏
页码:50 / 59
页数:10
相关论文
共 40 条
[1]  
An T, 2011, CHINESE J INORG CHEM, V27, P231
[2]   OXIDATION BEHAVIOR OF ALUMINUM NANOPOWDERS [J].
AUMANN, CE ;
SKOFRONICK, GL ;
MARTIN, JA .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1995, 13 (03) :1178-1183
[3]   Deposition and characterization of a self-propagating CuOx/Al thermite reaction in a multilayer foil geometry [J].
Blobaum, KJ ;
Reiss, ME ;
Lawrence, JMP ;
Weihs, TP .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (05) :2915-2922
[4]   Kinetic study of thermal- and impact-initiated reactions in Al-Fe2O3 nanothermite [J].
Cheng, J. L. ;
Hng, H. H. ;
Lee, Y. W. ;
Du, S. W. ;
Thadhani, N. N. .
COMBUSTION AND FLAME, 2010, 157 (12) :2241-2249
[5]   A method for testing the elastic modulus of single cellulose fibrils via atomic force microscopy [J].
Cheng, Qingzheng ;
Wang, Siquin .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2008, 39 (12) :1838-1843
[6]  
Clapsaddle B. J., 2003, MAT RES SOC FALL M N
[7]   Metal-based reactive nanomaterials [J].
Dreizin, Edward L. .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2009, 35 (02) :141-167
[8]   The effect of stoichiometry on the combustion behavior of a nanoscale Al/MoO3 thermite [J].
Dutro, G. M. ;
Yetter, R. A. ;
Risha, G. A. ;
Son, S. F. .
PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2009, 32 :1921-1928
[9]   Enabling and controlling slow reaction velocities in low-density compacts of multilayer reactive particles [J].
Fritz, Gregory M. ;
Joress, Howie ;
Weihs, Timothy P. .
COMBUSTION AND FLAME, 2011, 158 (06) :1084-1088
[10]   Laser ignition of nanocomposite thermites [J].
Granier, JJ ;
Pantoya, ML .
COMBUSTION AND FLAME, 2004, 138 (04) :373-383