Cyclotricatechylene based porous crystalline material: Synthesis and applications in gas storage

被引：129

作者：

Yu, Jin-Tao ^{[2
]}

Chen, Zhe ^{[2
]}

Sun, Junliang ^{[1
]}

Huang, Zhi-Tang ^{[2
]}

Zheng, Qi-Yu ^{[2
]}

机构：

[1] Stockholm Univ, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden

[2] Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 12期

基金：

中国国家自然科学基金;

关键词：

COVALENT ORGANIC FRAMEWORKS; INTRINSIC MICROPOROSITY; RETICULAR SYNTHESIS; HYDROGEN; CRYPTOPHANES; GENERATION; STABILITY; POLYMERS; CAPACITY; POROSITY;

D O I：

10.1039/c2jm15159f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An undulated two-dimensional CTC-based covalent organic framework, CTC-COF, was synthesized through solvothermal reaction for the first time. This mesoporous material stacks in an eclipsed mode in the microcrystalline state. CTC-COF has a surface area of 1710 m(2) g(-1), with a pore width of 2.26 nm calculated by the NL-DFT modelling. The bowl-shaped core unit led to a larger surface area than its analogue, COF-5 constructed by planar subunits. This material has higher low pressure hydrogen uptake than other 2D COFs with similar structures, and even close to the 3D COF materials.

引用

页码：5369 / 5373

页数：5

共 45 条

[21] Adsorption and diffusion of hydrogen and methane in 2D covalent organic frameworks [J].

Garberoglio, G. ;

Vallauri, R. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 116 (1-3) :540-547

[22] Covalent organic frameworks as exceptional hydrogen storage materials [J].

Han, Sang Soo ;

Furukawa, Hiroyasu ;

Yaghi, Omar M. ;

Goddard, William A., III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (35) :11580-+

[23] Recent advances in the chemistry of cyclotriveratrylene [J].

Hardie, Michaele J. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (02) :516-527

[24] Reticular synthesis of covalent organic borosilicate frameworks [J].

Hunt, Joseph R. ;

Doonan, Christian J. ;

LeVangie, James D. ;

Cote, Adrien P. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (36) :11872-11873

[25] THE NATURE OF PI-PI INTERACTIONS [J].

HUNTER, CA ;

SANDERS, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5525-5534

[26] Designing 3D COFs with Enhanced Hydrogen Storage Capacity [J].

Klontzas, Emmanouel ;

Tylianakis, Emmanuel ;

Froudakis, George E. .

NANO LETTERS, 2010, 10 (02) :452-454

[27] Enhanced Hydrolytic Stability of Self-Assembling Alkylated Two-Dimensional Covalent Organic Frameworks [J].

Lanni, Laura M. ;

Tilford, R. William ;

Bharathy, Muktha ;

Lavigne, John J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (35) :13975-13983

[28] The next generation of shape-persistant zeolite analogues: Covalent organic frameworks [J].

Mastalerz, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :445-447

[29] Towards polymer-based hydrogen storage materials: Engineering ultramicroporous cavities within polymers of intrinsic microporosity [J].

McKeown, NB ;

Ghanem, BS ;

Msayib, KJ ;

Budd, PM ;

Tattershall, CE ;

Mahmood, K ;

Tan, S ;

Book, D ;

Langmi, HW ;

Walton, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (11) :1804-1807

[30] STRUCTURE AND DYNAMICS OF PYRAMIDIC LIQUID-CRYSTALS BY DEUTERIUM NMR AND X-RAY-DIFFRACTION [J].

POUPKO, R ;

LUZ, Z ;

SPIELBERG, N ;

ZIMMERMANN, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) :6094-6105

← 1 2 3 4 5 →