Cyclotricatechylene based porous crystalline material: Synthesis and applications in gas storage

被引:127
|
作者
Yu, Jin-Tao [2 ]
Chen, Zhe [2 ]
Sun, Junliang [1 ]
Huang, Zhi-Tang [2 ]
Zheng, Qi-Yu [2 ]
机构
[1] Stockholm Univ, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden
[2] Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
COVALENT ORGANIC FRAMEWORKS; INTRINSIC MICROPOROSITY; RETICULAR SYNTHESIS; HYDROGEN; CRYPTOPHANES; GENERATION; STABILITY; POLYMERS; CAPACITY; POROSITY;
D O I
10.1039/c2jm15159f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An undulated two-dimensional CTC-based covalent organic framework, CTC-COF, was synthesized through solvothermal reaction for the first time. This mesoporous material stacks in an eclipsed mode in the microcrystalline state. CTC-COF has a surface area of 1710 m(2) g(-1), with a pore width of 2.26 nm calculated by the NL-DFT modelling. The bowl-shaped core unit led to a larger surface area than its analogue, COF-5 constructed by planar subunits. This material has higher low pressure hydrogen uptake than other 2D COFs with similar structures, and even close to the 3D COF materials.
引用
收藏
页码:5369 / 5373
页数:5
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