Cyclotricatechylene based porous crystalline material: Synthesis and applications in gas storage

被引：129

作者：

Yu, Jin-Tao ^{[2
]}

Chen, Zhe ^{[2
]}

Sun, Junliang ^{[1
]}

Huang, Zhi-Tang ^{[2
]}

Zheng, Qi-Yu ^{[2
]}

机构：

[1] Stockholm Univ, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden

[2] Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 12期

基金：

中国国家自然科学基金;

关键词：

COVALENT ORGANIC FRAMEWORKS; INTRINSIC MICROPOROSITY; RETICULAR SYNTHESIS; HYDROGEN; CRYPTOPHANES; GENERATION; STABILITY; POLYMERS; CAPACITY; POROSITY;

D O I：

10.1039/c2jm15159f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An undulated two-dimensional CTC-based covalent organic framework, CTC-COF, was synthesized through solvothermal reaction for the first time. This mesoporous material stacks in an eclipsed mode in the microcrystalline state. CTC-COF has a surface area of 1710 m(2) g(-1), with a pore width of 2.26 nm calculated by the NL-DFT modelling. The bowl-shaped core unit led to a larger surface area than its analogue, COF-5 constructed by planar subunits. This material has higher low pressure hydrogen uptake than other 2D COFs with similar structures, and even close to the 3D COF materials.

引用

页码：5369 / 5373

页数：5

共 45 条

[1]

[Anonymous], 2009, MS MOD 5 0

[2] Rational Extension of the Family of Layered, Covalent, Triazine-Based Frameworks with Regular Porosity [J].

Bojdys, Michael J. ;

Jeromenok, Jekaterina ;

Thomas, Arne ;

Antonietti, Markus .

ADVANCED MATERIALS, 2010, 22 (19) :2202-+

[3] Cryptophanes and Their Complexes-Present and Future [J].

Brotin, Thierry ;

Dutasta, Jean-Pierre .

CHEMICAL REVIEWS, 2009, 109 (01) :88-130

[4] Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks [J].

Campbell, Neil L. ;

Clowes, Rob ;

Ritchie, Lyndsey K. ;

Cooper, Andrew I. .

CHEMISTRY OF MATERIALS, 2009, 21 (02) :204-206

[5] Lithium-Doped 3D Covalent Organic Frameworks: High-Capacity Hydrogen Storage Materials [J].

Cao, Dapeng ;

Lan, Jianhui ;

Wang, Wenchuan ;

Smit, Berend .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (26) :4730-4733

[6]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[7]

2-U

[8] CYCLOTRIVERATRYLENES AND CRYPTOPHANES [J].

COLLET, A .

TETRAHEDRON, 1987, 43 (24) :5725-5759

[9]

COLLET A, 1993, TOP CURR CHEM, V165, P103

[10] Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks [J].

Cote, Adrien P. ;

El-Kaderi, Hani M. ;

Furukawa, Hiroyasu ;

Hunt, Joseph R. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :12914-+

← 1 2 3 4 5 →