A hierarchical three-dimensional NiCo2O4 nanowire array/carbon cloth as an air electrode for nonaqueous Li-air batteries

被引:83
作者
Liu, Wei-Ming [1 ]
Gao, Ting-Ting [2 ]
Yang, Yin [1 ]
Sun, Qian [1 ]
Fu, Zheng-Wen [1 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[2] Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China
关键词
RECHARGEABLE LI-O-2 BATTERIES; LITHIUM-OXYGEN BATTERIES; GRAPHENE NANOSHEETS; PERFORMANCE; ELECTROCATALYSTS; CATALYST; LI2O2; SUPERCAPACITORS; CAPACITY;
D O I
10.1039/c3cp52773e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A 3D NiCo2O4 nanowire array/carbon cloth (NCONW/CC) was employed as the cathode for Li-air batteries with a non-aqueous electrolyte. After its discharge, novel porous ball-like Li2O2 was found to be deposited on the tip of NiCo2O4 nanowires. The special structure of Li2O2 and active sites of catalysts are also discussed.
引用
收藏
页码:15806 / 15810
页数:5
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