Synthesis of Dibenzopyranones through Palladium-Catalyzed Directed C-H Activation/Carbonylation of 2-Arylphenols

被引：149
|
作者：
Luo, Shuang [1 ,2 ]
Luo, Fei-Xian [1 ,2 ]
Zhang, Xi-Sha [1 ,2 ]
Shi, Zhang-Jie [1 ,2 ,3 ]
机构：
[1] Peking Univ, BNLMS, PKU Green Chem Ctr, Coll Chem, Beijing 100871, Peoples R China
[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 40期
关键词：
carbonylation; C-H activation; dibenzopyranone; phenol; synthetic methods; BIARYL COUPLING REACTION; DIRECT CARBONYLATION; C(SP(3))-H BONDS; BENZENE-RING; ARYL; LACTONIZATION; RU-3(CO)(12); LACTONES; ENTRY;
D O I：
10.1002/anie.201304295
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dibenzopyranones were synthesized by a palladium-catalyzed phenol-directed C-H activation/carbonylation of 2-phenylphenol derivatives in the presence of CO. Pd(OAc)2 was used as a catalyst and Cu(OAc)2 as a catalytic oxidant in the presence of air. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10598 / 10601
页数：4
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