Synthesis of Dibenzopyranones through Palladium-Catalyzed Directed C-H Activation/Carbonylation of 2-Arylphenols

被引：149

作者：

Luo, Shuang ^{[1
,2
]}

Luo, Fei-Xian ^{[1
,2
]}

Zhang, Xi-Sha ^{[1
,2
]}

Shi, Zhang-Jie ^{[1
,2
,3
]}

机构：

[1] Peking Univ, BNLMS, PKU Green Chem Ctr, Coll Chem, Beijing 100871, Peoples R China

[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[3] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 40期

关键词：

carbonylation; C-H activation; dibenzopyranone; phenol; synthetic methods; BIARYL COUPLING REACTION; DIRECT CARBONYLATION; C(SP(3))-H BONDS; BENZENE-RING; ARYL; LACTONIZATION; RU-3(CO)(12); LACTONES; ENTRY;

D O I：

10.1002/anie.201304295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dibenzopyranones were synthesized by a palladium-catalyzed phenol-directed C-H activation/carbonylation of 2-phenylphenol derivatives in the presence of CO. Pd(OAc)2 was used as a catalyst and Cu(OAc)2 as a catalytic oxidant in the presence of air. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10598 / 10601

页数：4

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