An Adsorbent Performance Indicator as a First Step Evaluation of Novel Sorbents for Gas Separations: Application to Metal-Organic Frameworks

被引：131

作者：

Wiersum, Andrew D. ^{[1
]}

Chang, Jong-San ^{[2
]}

Serre, Christian ^{[3
]}

Llewellyn, Philip L. ^{[1
]}

机构：

[1] Aix Marseille Univ, Ctr St Jerome, CNRS UMR7246, Lab MADIREL, F-13397 Marseille 20, France

[2] Korea Res Inst Chem Technol, Biorefinery Res Ctr, Res Grp Nanocatalyst, Taejon 305600, South Korea

[3] Univ Versailles St Quentin Yvelines, CNRS UMR8180, Inst Lavoisier, F-78035 Versailles, France

来源：

LANGMUIR | 2013年 / 29卷 / 10期

关键词：

CARBON-DIOXIDE CAPTURE; MOLECULAR SIMULATIONS; POROUS MATERIALS; CO2; ADSORPTION; MICROCALORIMETRY; CH4; MIXTURES; MIL-100; MOFS;

D O I：

10.1021/la3044329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An adsorbent performance indicator (API) is proposed in an effort to initially highlight porous materials of potential interest for PSA separation processes. This expression takes into account working capacities, selectivities, and adsorption energies and additionally uses weighting factors to reflect the specific requirements of a given process. To demonstrate the applicability of the API, we have performed the adsorption of carbon dioxide and methane at room temperature on a number of metal-organic frameworks, a zeolite and a molecular sieve carbon. The API is calculated for two different CO2/CH4 separation case scenarios: "bulk separation" and "natural gas purification". This comparison highlights how the API can be more versatile than previously proposed comparison factors for an initial indication of potential adsorbent performance.

引用

页码：3301 / 3309

页数：9

共 60 条

[1] Ackley M, 2000, Patent No. [US6027548A, 6027548]
[2] Ackley M. W., 1998, EP875279A2, Patent No. [875279, EP875279A2]
[3] [Anonymous], 1998, ADSORPTION ANALYSISE
[4] Development and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture
Bae, Youn-Sang
Snurr, Randall Q.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (49) : 11586 - 11596
[5] Baksh M. S. A., 1998, Method for production of nitrogen using oxygen selective adsorbents, Patent No. [US5735938A, 5735938]
[6] Adsorption of Ethane, Ethylene, Propane, and Propylene on a Magnesium-Based Metal-Organic Framework
Bao, Zongbi
Alnemrat, Sufian
Yu, Liang
Vasiliev, Igor
Ren, Qilong
Lu, Xiuyang
Deng, Shuguang
[J]. LANGMUIR, 2011, 27 (22) : 13554 - 13562
[7] Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
Bloch, Eric D.
Queen, Wendy L.
Krishna, Rajamani
Zadrozny, Joseph M.
Brown, Craig M.
Long, Jeffrey R.
[J]. SCIENCE, 2012, 335 (6076) : 1606 - 1610
[8] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability
Cavka, Jasmina Hafizovic
Jakobsen, Soren
Olsbye, Unni
Guillou, Nathalie
Lamberti, Carlo
Bordiga, Silvia
Lillerud, Karl Petter
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) : 13850 - 13851
[9] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
Chui, SSY
Lo, SMF
Charmant, JPH
Orpen, AG
Williams, ID
[J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
[10] Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, Deanna M.
Smit, Berend
Long, Jeffrey R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) : 6058 - 6082

← 1 2 3 4 5 6 →