Synthesis and crystal structure of 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin

被引：0
作者：
Bhyrappa, P [1 ]
Suslick, KS [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 1998年 / 2卷 / 4-5期
关键词：
tetraphenylporphyrin; tetraarylporphyrin; nitroporphyrin; synthesis; X-ray crystallography; structure determination;
D O I：
10.1002/(SICI)1099-1409(199807/10)2:4/5<391::AID-JPP95>3.3.CO;2-L
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis, characterization and crystal structure of the octanitro-substituted porphyrin 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin H2T(3,5-DNP)P, are described. The solid state structure has two porphyrins in the unit cell with eight pyridine solvates and is made up from columnar arrays of the porphyrins. X-ray crystal structure data: monoclinic, space group P1 2(1)/n1, a = 14.9996(9) Angstrom, b = 8.2489(5) Angstrom, c = 24.818(2) Angstrom, alpha = 90 degrees, beta = 104.172(1)degrees, gamma = 90 degrees, V = 2977.3(3) Angstrom(3), d(calc) = 1.440 g m(-3), Z = 2. (C) 1998 John Wiley & Sons, Ltd.
引用
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页码：391 / 396
页数：6
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