Diffusion coefficients of molecular iodine in aqueous solutions

被引：28
|
作者：
Cantrel, L
Chaouche, R
ChopinDumas, J
机构：
[1] ECOLE NATL SUPER SYNTH,ELECTROCHIM INORGAN LAB,F-13397 MARSEILLE,FRANCE
[2] CEA CADARACHE,IPSN DRS SREAS,INST PROTECT & SURETE NUCL,F-13108 ST PAUL DURANCE,FRANCE
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1997年 / 42卷 / 01期
关键词：
D O I：
10.1021/je960178u
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The diffusion coefficients of iodine in 0.075 mol dm(-3) sulfuric acid have been determined between 298 K and 358 K, by measuring the Limiting reduction currents at a platinum rotating disk electrode. A Stokes-Einstein relation is verified over the range of temperature studied. The experimental value obtained at 298 K is compared with some available relations for the estimation of diffusion coefficients at infinite dilution. The agreement is good.
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收藏
页码：216 / 220
页数：5
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