Towards sixfold functionalization of buckminsterfullerene (C60) at fully addressable octahedral sites

被引：0

作者：

Qian, WY ^{[1
]}

Rubin, Y ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 16期

关键词：

cycloadditions; Diels-Alder reactions; diimines; fullerenes; semiempirical calculations;

D O I：

10.1002/(SICI)1521-3773(19990816)38:16<2356::AID-ANIE2356>3.0.CO;2-Y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective C60-functionalizations that provide access to unusual multifunctional molecules are of interest in the construction of highly organized three-dimensional assemblies. The temporary 'masking' of three of the most reactive sites on C60 by a bisdiene tether has allowed the facile and high-yielding formation of the fully differentiated trisadduct I and the interesting hexaadduct 2.

引用

页码：2356 / 2360

页数：5

共 50 条

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