One-dimensional alignment of organometallic donor-acceptor compounds via coordination polymerization. Synthesis and structures of [W(CC6H4X-4)(OBut)(3)](infinity) (X=MMe2, SMe)

被引：43

作者：

Brison, HA

Pollagi, TP

Stoner, TC

Geib, SJ

Hopkins, MD

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

[2] UNIV PITTSBURGH,MAT RES CTR,PITTSBURGH,PA 15260

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 14期

关键词：

D O I：

10.1039/a701046j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-alkylidyne complexes of the type W(=CC6H4X-4)(OBut)(3) (X = NMe2, SMe), which are analogues of classic organic donor-acceptor compounds, form infinite-chain structures in the solid state through weak intermolecular dative bonds between the tungsten and donor atoms.

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页码：1263 / 1264

页数：2

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