A silicon-cobalt cluster with an unusually short cross-ring silicon-silicon distance

被引:15
作者
Bourg, S [1 ]
Boury, B [1 ]
Carre, F [1 ]
Corriu, RJP [1 ]
机构
[1] UNIV MONTPELLIER 2,UMR 5637,CC 007,F-34095 MONTPELLIER 5,FRANCE
关键词
D O I
10.1021/om9701276
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
[mu-((CH3)Si(CH2)-)(2)](Co(CO)(3))(2) was formed in the reaction of 2,5-disilahexane with dicobalt octacarbonyl. The complex was fully characterized, and the X-ray diffraction crystal structure indicates a very short Si ... Si transannular distance.
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页码:3097 / 3099
页数:3
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