Thermoresponsive polymers in non-aqueous solutions

被引:22
作者
Concilio, Matilde [1 ]
Beyer, Valentin P. [1 ,2 ]
Becer, C. Remzi [1 ,2 ]
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, England
[2] Queen Mary Univ London, Sch Engn & Mat Sci, Polymer Chem Lab, London E1 4NS, England
关键词
CRITICAL SOLUTION TEMPERATURE; ALT-MALEIC ANHYDRIDE); LCST PHASE-BEHAVIOR; POST-POLYMERIZATION MODIFICATION; RAFT DISPERSION POLYMERIZATION; STIMULI-RESPONSIVE POLYMERS; WATER-DIOXANE MIXTURES; IONIC LIQUIDS; BLOCK-COPOLYMER; DIBLOCK COPOLYMERS;
D O I
10.1039/d2py01147f
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Thermoresponsive polymers are gaining increasing interest for numerous applications especially in the biomedical and nanotechnology fields. The thermoresponsive behaviour of polymers has been extensively studied in pure water or water/organic solvent systems, however, temperature-induced phase transitions in other organic solvents are less common. Polymers in organic solvents exhibit a broad range of temperature-driven solution behaviours, from LCST and UCST, to sol-gel transitions, to micellization processes, among others, with potential applications as smart materials in electronics, in the lubricant industry, and in the biomedical field. This review article will focus on the thermoresponsive behaviour of polymers in different classes of organic solvents and mixtures thereof to emphasize and demonstrate the versatility and potential of these polymers.
引用
收藏
页码:6423 / 6474
页数:52
相关论文
共 209 条
[1]   Thermoreversible morphology transitions of poly(styrene-b-dimethylsiloxane) diblock copolymer micelles in dilute solution [J].
Abbas, Sayeed ;
Li, Zhibo ;
Hassan, Hassan ;
Lodge, Timothy P. .
MACROMOLECULES, 2007, 40 (11) :4048-4052
[2]   Stimuli responsive polymers for biomedical applications [J].
Alarcón, CDH ;
Pennadam, S ;
Alexander, C .
CHEMICAL SOCIETY REVIEWS, 2005, 34 (03) :276-285
[3]   POLY(ETHYLENE OXIDE)-POLY(PROPYLENE OXIDE)-POLY(ETHYLENE OXIDE) BLOCK-COPOLYMER SURFACTANTS IN AQUEOUS-SOLUTIONS AND AT INTERFACES - THERMODYNAMICS, STRUCTURE, DYNAMICS, AND MODELING [J].
ALEXANDRIDIS, P ;
HATTON, TA .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1995, 96 (1-2) :1-46
[4]   Thermoresponsivity of polymer solution derived from a self-attractive urea unit and a self-repulsive lipophilic ion unit [J].
Amemori, Shogo ;
Iseda, Kazuya ;
Anan, Shizuka ;
Ono, Toshikazu ;
Kokado, Kenta ;
Sada, Kazuki .
POLYMER CHEMISTRY, 2017, 8 (26) :3921-3925
[5]   Polymer Phase-Transition Behavior Driven by a Charge-Transfer Interaction [J].
Amemori, Shogo ;
Kokado, Kenta ;
Sada, Kazuki .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (15) :4174-4178
[6]   Fundamental Molecular Design for Precise Control of Thermoresponsiveness of Organic Polymers by Using Ternary Systems [J].
Amemori, Shogo ;
Kokado, Kenta ;
Sada, Kazuki .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (20) :8344-8347
[7]   Polyacrylamide "revisited'': UCST-type reversible thermoresponsive properties in aqueous alcoholic solutions [J].
Asadujjaman, Asad ;
de Oliveira, Tiago Espinosa ;
Mukherji, Debashish ;
Bertin, Annabelle .
SOFT MATTER, 2018, 14 (08) :1336-1343
[8]   Thermoresponsive functional polymers based on 2,6-diaminopyridine motif with tunable UCST behaviour in water/alcohol mixtures [J].
Asadujjaman, Asad ;
Ahmadi, Vahid ;
Yalcin, Meral ;
ten Brummelhuis, Niels ;
Bertin, Annabelle .
POLYMER CHEMISTRY, 2017, 8 (20) :3140-3153
[9]   Non-ionic Thermoresponsive Polymers in Water [J].
Aseyev, Vladimir ;
Tenhu, Heikki ;
Winnik, Francoise M. .
SELF ORGANIZED NANOSTRUCTURES OF AMPHIPHILIC BLOCK COPOLYMERS II, 2011, 242 :29-89
[10]   Non-linear PEG-based thermoresponsive polymer systems [J].
Badi, Nezha .
PROGRESS IN POLYMER SCIENCE, 2017, 66 :54-79