Strutural and optical approach of CdS@ZnS core-shell system

被引:42
作者
Raubach, Cristiane W. [1 ]
de Santana, Yuri V. B. [1 ]
Ferrer, Mateus M. [1 ]
Longo, Valeria M. [2 ]
Varela, Jose A. [2 ]
Avansi, Waldir, Jr. [2 ]
Buzolin, Prescila G. C. [3 ]
Sambrano, Julio R. [3 ]
Longo, Elson [2 ]
机构
[1] Univ Fed Sao Carlos, INCTMN UFSCar, BR-13565905 Sao Carlos, SP, Brazil
[2] Univ Estadual Paulista, INCTMN UNESP, BR-14801907 Araraquara, SP, Brazil
[3] Univ Estadual Paulista, INCTMN UNESP, BR-17033360 Bauru, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
HARTREE-FOCK; PHOTOLUMINESCENCE; NANOPARTICLES;
D O I
10.1016/j.cplett.2012.03.090
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An intense red-green photoluminescence (PL) emission was observed, at room temperature, in a CdS@ZnS core-shell system. The PL intensity emission of CdS@ZnS core-shell was strongly superior from that observed in individual CdS and ZnS nanoparticles. In this sense, we reported a comprehensive experimental and theoretical study of the optical behavior of CdS and ZnS nanoparticles (NPs), and CdS@ZnS core-shell system in the light the structural order-disorder conception. We also propose a model were the core and shell interface leads to favorable condition that triggers PL emission in CdS@ZnS core-shell. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:96 / 99
页数:4
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