Mechanochemical and sonochemical heterocyclizations

被引：8
作者：
Gaudino, Emanuela Calcio [1 ,2 ]
Tagliapietra, Silvia [1 ,2 ]
Mantegna, Stefano [1 ,2 ]
Cravotto, Giancarlo [1 ,2 ]
机构：
[1] Univ Turin, Dipartimento Sci & Tecnol Farmaco, Via P Giuria 9, I-10125 Turin, Italy
[2] Univ Turin, NIS Ctr Nanostruct Interfaces & Surfaces, Via P Giuria 9, I-10125 Turin, Italy
来源：
CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2016年 / 52卷 / 11期
关键词：
heterocycles; ball mill; cyclization; green chemistry; ultrasound; ULTRASOUND-ASSISTED SYNTHESIS; ONE-POT SYNTHESIS; MULTICOMPONENT REACTIONS; EFFICIENT SYNTHESIS; GREEN SYNTHESIS; N-HETEROCYCLES; RAPID PROTOCOL; AQUEOUS-MEDIA; IRRADIATION; CATALYST;
D O I：
10.1007/s10593-017-1979-y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Heterocycle formation reactions require efficient catalysis and suitable physical activation. Sonochemistry and mechanochemistry can dramatically promote heterocyclizations in heterogeneous conditions using benign solvents and even in solventless conditions by means of ball mills. Besides facilitating quick cyclization, these technologies bring with them safer protocols, cost reduction, energy saving, process intensification, and waste minimization. The aim of this review is to describe a number of relevant synthetic advances in the last two years and to highlight the huge unexploited potential of both sonochemistry and mechanochemistry.
引用
收藏
页码：856 / 865
页数：10
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