Recent NMR developments applied to organic-inorganic materials

被引:72
作者
Bonhomme, Christian [1 ]
Gervais, Christel [1 ]
Laurencin, Danielle [2 ]
机构
[1] Univ Paris 06, CNRS, Coll France, Lab Chim Mat Condensee Paris,UMR 7574, F-75231 Paris 05, France
[2] ENSCM, CNRS, Inst Charles Gerhardt Montpellier, UMR5253,UM2,UM1,CC1701, F-34095 Montpellier, France
关键词
Solid state NMR; Organic-inorganic materials; Hybrid materials; Interface; Structure; SOLID-STATE NMR; NUCLEAR-MAGNETIC-RESONANCE; PULSED-FIELD-GRADIENT; LAYERED DOUBLE HYDROXIDES; ANGLE-SPINNING NMR; DENSITY-FUNCTIONAL THEORY; PRUSSIAN BLUE ANALOGS; FLUORINATED GALLIUM PHOSPHATE; MESOPOROUS BIOACTIVE GLASSES; DIPOLAR DECOUPLING SCHEMES;
D O I
10.1016/j.pnmrs.2013.10.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this contribution, the latest developments in solid state NMR are presented in the field of organic-inorganic (O/I) materials (or hybrid materials). Such materials involve mineral and organic (including polymeric and biological) components, and can exhibit complex O/I interfaces. Hybrids are currently a major topic of research in nanoscience, and solid state NMR is obviously a pertinent spectroscopic tool of investigation. Its versatility allows the detailed description of the structure and texture of such complex materials. The article is divided in two main parts: in the first one, recent NMR methodological/instrumental developments are presented in connection with hybrid materials. In the second part, an exhaustive overview of the major classes of O/I materials and their NMR characterization is presented. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 48
页数:48
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