Deal;Photoredox Catalysis for the Cycloaddition Reactions

被引:30
作者
Zhang, Tong [1 ,2 ]
Zhang, Yu [1 ]
Das, Shoubhik [1 ]
机构
[1] Univ Antwerp, Dept Chem, ORSY Div, Campus Groenenborger,Groenenborgerlaan 171, B-2020 Antwerp, Belgium
[2] Georg August Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany
关键词
photoredox; cycloaddition; visible light; one-electron transfer; energy transfer; VISIBLE-LIGHT PHOTOCATALYSIS; METAL-FREE CATALYST; INTERMOLECULAR 2+2 CYCLOADDITION; DIELS-ALDER CYCLOADDITIONS; FORMAL 4+2 CYCLOADDITION; PHOTOCYCLOADDITION REACTIONS; ACID CATALYSIS; PHOTOCHEMISTRY; DERIVATIVES; OXIDATION;
D O I
10.1002/cctc.202001195
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cycloaddition reaction is a powerful tool for the synthesis of cyclic structures in a green way. High-energy ultraviolet (UV) light was strictly required for the traditional photochemical processes. However, in the past ten years, discovery of photoredox catalysis for the cycloaddition reactions have attracted significant attention. Based on these elegant works, this review will summarize recent progresses in the visible-light-induced [2+2] and [4+2] cycloaddition reactions.
引用
收藏
页码:6173 / 6185
页数:13
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