Fe-catalyzed thermal conversion of sodium lignosulfonate to graphene

被引:41
作者
Mun, Sung Phil [1 ]
Cai, Zhiyong [2 ]
Zhang, Jilei [3 ]
机构
[1] Chonbuk Natl Univ, Dept Wood Sci & Technol, Jeonju 561756, Jeonbuk, South Korea
[2] US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA
[3] Mississippi State Univ, Dept Forest Prod, Mississippi State, MS 39762 USA
基金
美国国家科学基金会;
关键词
Lignosulfonate; Sulfite pulping; Fe nanoparticles; Graphene; Thermal treatment; Raman spectrum; WOOD; CARBON; SHEETS;
D O I
10.1016/j.matlet.2013.02.101
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sodium lignosulfonate (LS) from sulfite pulping processing was used as a carbon source to synthesize graphene. LS was mixed with Fe nanoparticles (FeNPs) as a catalyst and thermally treated at 1000 C for 1 h. The Raman spectrum and X-ray diffraction pattern suggested that graphene sheets were formed in LS thermally treated with FeNPs (Fe-HTLS). Scanning electron microscopy image of Fe-HTLS showed clusters of thin graphene sheets appearing in the form of nanoflowers. High-resolution transmission electron microscopy and electron reflection images provided further evidence of the formation of graphene in LS thermally treated in the presence of Fe catalyst. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:180 / 183
页数:4
相关论文
共 16 条
[1]   Carbonized wood monoliths - Characterization [J].
Byrne, CE ;
Nagle, DC .
CARBON, 1997, 35 (02) :267-273
[2]   Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy [J].
Dresselhaus, Mildred S. ;
Jorio, Ado ;
Hofmann, Mario ;
Dresselhaus, Gene ;
Saito, Riichiro .
NANO LETTERS, 2010, 10 (03) :751-758
[3]  
Du YC, 2010, FOREST PROD J, V60, P527
[4]   Co-ordination network for lignin -: standardisation, production and applications adapted to market requirements (EUROLIGNIN) [J].
Gosselink, RJA ;
de Jong, E ;
Guran, B ;
Abächerli, A .
INDUSTRIAL CROPS AND PRODUCTS, 2004, 20 (02) :121-129
[5]   Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries [J].
Guo, Peng ;
Song, Huaihe ;
Chen, Xiaohong .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (06) :1320-1324
[6]   Microstructural investigation of wood charcoal made by spark plasma sintering [J].
Hata, T ;
Yamane, K ;
Kobayashi, E ;
Imamura, Y ;
Ishihara, S .
JOURNAL OF WOOD SCIENCE, 1998, 44 (04) :332-334
[7]   Preparation of graphene nanowalls by a simple microwave-based method [J].
Hojati-Talemi, Pejman ;
Simon, George P. .
CARBON, 2010, 48 (14) :3993-4000
[8]   Characterization of sp2- and sp3-bonded carbon in wood charcoal [J].
Ishimaru, Kengo ;
Hata, Toshimitsu ;
Bronsveld, Paul ;
Nishizawa, Takashi ;
Imamura, Yuji .
JOURNAL OF WOOD SCIENCE, 2007, 53 (05) :442-448
[9]   Spectroscopic analysis of carbonization behavior of wood, cellulose and lignin [J].
Ishimaru, Kengo ;
Hata, Toshimitsu ;
Bronsveld, Paul ;
Meier, Dietrich ;
Imamura, Yuji .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (01) :122-129
[10]   Easy synthesis and characterization of high quality graphene sheets produced from mesocarbon microbeads [J].
Kong, Ying ;
Zhao, Dong-Lin ;
Bai, Li-Zhong ;
Shen, Zeng-Min .
MATERIALS LETTERS, 2011, 65 (17-18) :2739-2741