Synthesis and Crystal Structure of N-(2-(1-buty1-3-phenylureido)-1Hindo1-3-y1)-N-(4-chlorophenyl)benzamideC)

被引：0

作者：

He Ping ^{[1
,2
]}

Ding Ming-Wu ^{[3
]}

机构：

[1] Hubei Univ Arts & Sci, Coll Chem Engn & Food Sci, Xiangyang 441053, Peoples R China

[2] Hubei Univ Arts & Sci, Res Ctr Mat Sci & Engn, Xiangyang 441053, Peoples R China

[3] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 32卷 / 02期

基金：

中国国家自然科学基金;

关键词：

synthesis; crystal structure; indole; rearrangement; UNEXPECTED SYNTHESIS; EFFICIENT SYNTHESIS; DERIVATIVES; IMIDAZOLES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound N-(2-(1-buty1-3-phenylureido)-1H-indo1-3-y1)-N-(4-chloropheny1)-benzamide (C32H29CIN4O2, M-r = 537.04) was synthesized by a sequential Ugi four component condensation (4CC)/aza-Wiftig/carbodiimide-mediated cyclization, and the structure was characterized by NMR, IR, MS, elemental analysis and X-ray single-crystal diffraction analysis. The crystal belongs to orthorhombic, space group P2(1)2(1)2(1) with a = 11.3663(9), b = 13.3248(10), c = 18.7887(15) angstrom, V= 2845.6(4) angstrom(3), Z= 4, De= 1.254 mg/m(3), mu = 0.170 mm-1, F(000) = 1128, the final R = 0.0538 and wR = 0.1187. X-ray analysis reveals that the new five-membered ring (C(14) C(15) N(2) C(16) C(21)) and the benzene ring (C(16) C(21)) are nearly coplanar.

引用

页码：306 / 310

页数：5

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