New bivalent germanium, tin and lead compounds with M-O bond

被引：22

作者：

Barrau, J

Rima, G

ElAmraoui, T

机构：

[1] Lab. d'Heterochimie Fond. et Appl., URA No. 477 du CNRS, Université Paul-Sabatier, 31062 Toulouse Cedex

来源：

INORGANICA CHIMICA ACTA | 1996年 / 241卷 / 02期

关键词：

germanium complexes; tin complexes; lead complexes; bivalent complexes;

D O I：

10.1016/0020-1693(95)04977-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of new stable bivalent germanium, tin and lead homoleptic species (ArO)(2)M: (ArO = 2,4,6-[(CH3)(2)NCH2]3C6H2O; M=Ge (1), Sn (2), Pb (3)), Ge(OSO2CF3)(2) . C4H8O2 (4) and heteroleptic species M(OAr) [N(SiMe(3))(2)] (M = Ge (5), Sn (6)) are described. New organometallic heterocycles, stable metalla-imines and germathione (ArO)(2)M = X (X = NSiMe(3), S) and metal(II)-transition metal complexes are obtained starting from 1 and 2.

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页码：9 / 10

页数：2

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