Assessment of thermo-structural properties of Al-Fe and Fe-Si alloys at high temperatures

被引:2
作者
Gohivar, R. K. [1 ,2 ]
Yadav, S. K. [2 ]
Koirala, R. P. [2 ]
Adhikari, D. [2 ]
机构
[1] Tribhuvan Univ, Cent Dept Phys, Kathmandu, Nepal
[2] Tribhuvan Univ, Dept Phys, Mahendra Morang Adarsh Multiple Campus, Biratnagar, Nepal
关键词
Fe-based alloy; artefacts; thermo-structural properties; interaction parameters; R-K polynomial; CONCENTRATION FLUCTUATIONS; THERMODYNAMIC PROPERTIES; LIQUID; ASYMMETRY;
D O I
10.1080/00319104.2020.1793985
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The thermodynamic and structural properties of Fe - based (Al-Fe and Fe-Si) alloys in their liquid states at different higher temperatures have been studied assuming the interaction parameters of R-K polynomial are linearly and exponentially dependent on temperature. It has been observed that artificial miscibility gaps (also called artefacts) appear in the thermodynamic and structural properties of the aforementioned alloys at high temperature when the interaction parameters are assumed to be linearly dependent on temperature. The artificial miscibility gaps or artefacts observed in the former case are eliminated when the interaction parameters are supposed to be exponentially dependent on temperature. This implies that the interaction parameters of RK-polynomial for liquid alloys vary exponentially at elevated temperatures.
引用
收藏
页码:679 / 689
页数:11
相关论文
共 30 条
[1]   Disorder in liquid Cu-Pd alloys [J].
Adhikari, D. .
PHASE TRANSITIONS, 2011, 84 (04) :308-314
[2]   Structural and energetic asymmetry in liquid Ag-Al alloys [J].
Adhikari, D. ;
Singh, B. P. ;
Jha, I. S. .
PHYSICS AND CHEMISTRY OF LIQUIDS, 2010, 48 (06) :787-796
[3]   Structural asymmetry in liquid Fe-Si alloys [J].
Adhikari, D. ;
Jha, I. S. ;
Singh, B. P. .
PHILOSOPHICAL MAGAZINE, 2010, 90 (20) :2687-2694
[4]  
Ansara I., 1998, COST, V507, P2
[5]   CONCENTRATION FLUCTUATIONS AND THERMODYNAMIC PROPERTIES OF SOME COMPOUND FORMING BINARY MOLTEN SYSTEMS [J].
BHATIA, AB ;
HARGROVE, WH .
PHYSICAL REVIEW B, 1974, 10 (08) :3186-3196
[6]   A QUASI-LATTICE THEORY FOR COMPOUND FORMING MOLTEN ALLOYS [J].
BHATIA, AB ;
SINGH, RN .
PHYSICS AND CHEMISTRY OF LIQUIDS, 1984, 13 (03) :177-190
[7]   Thermodynamics of high polymer solutions [J].
Flory, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1942, 10 (01) :51-61
[8]  
Fuxiao Y, 2014, MATER SCI ENG, V63, P012079
[9]  
Hultgren R., 1973, SELECTED VALUES THER
[10]  
Jha, 2014, J CHIN ADV MAT SOC, V2, P149, DOI DOI 10.1080/22243682.2014.928603