Epoxidation of syndiotactic 1,2-polybutadiene with peracids

被引：9

作者：

Abdullin, M. I. ^{[1
]}

Basyrov, A. A. ^{[1
]}

Kukovinets, O. S. ^{[1
]}

Glazyrin, A. B. ^{[1
]}

Khamidullina, G. I. ^{[1
]}

机构：

[1] Bashkir State Univ, Ufa 450078, Bashkortostan, Russia

来源：

POLYMER SCIENCE SERIES B | 2013年 / 55卷 / 5-6期

关键词：

POLYBUTADIENE; ACID;

D O I：

10.1134/S1560090413060018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The epoxidation of syndiotactic 1,2-polybutadiene (84 and 16% 1,2 and 1,4 units, respectively) with carboxylic peracids prepared in situ and m-chloroperbenzoic acid was studied. In the course of epoxidation in the presence of carboxylic peracids, oxirane groups are formed only through epoxidation of double bonds in the macromolecular backbone, whereas m-chloroperbenzoic acid is responsible for the chemical modification of 1,2 and 1,4 units of polybutadiene. The basic kinetic parameters of 1,2-polybutadiene epoxidation with peracids of various chemical structures were determined.

引用

页码：349 / 354

页数：6

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