Constructing and controlling ruthenium active phases for acetylene hydrochlorination

被引：30
|
作者：
Wang, Bolin [1 ,2 ]
Yue, Yuxue [1 ]
Wang, Saisai [1 ]
Chen, Zhi [1 ]
Yu, Lu [1 ]
Shao, Shujuan [1 ]
Lan, Guojun [1 ]
Pan, Zhiyan [2 ]
Zhao, Jia [1 ]
Li, Xiaonian [1 ]
机构：
[1] Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Tech, Ind Catalysis Inst, Hangzhou 310014, Peoples R China
[2] Zhejiang Univ Technol, Coll Environm, Hangzhou 310014, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 73期
基金：
中国国家自然科学基金;
关键词：
GOLD CATALYSTS; CARBON; NITROGEN; EFFICIENT; HYDROGENATION; NANOPARTICLES; PERFORMANCE;
D O I：
10.1039/d0cc04382f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ru-Based catalysts with distinct active phases from Ru-0, to RuO2, RuCl(3)and RuCl2N were synthesized and evaluated in acetylene hydrochlorination. RuCl2N is identified as the efficient active phase due to its co-activation of acetylene and hydrogen chloride. This discovery holds great potential to accelerate the large-scale application of Ru-based catalysts in industry.
引用
收藏
页码：10722 / 10725
页数：4
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