One-Pot Synthesis of Dimethyl Carbonate from Methanol, Propylene Oxide and Carbon Dioxide Over Supported Choline hydroxide/MgO

被引：36
作者：
De, Chunyan
Lu, Bin
Lv, He
Yu, Yuanyuan
Bai, Yu
Cai, Qinghai [1 ]
机构：
[1] Harbin Normal Univ, Coll Chem & Chem Engn, Harbin 150080, Peoples R China
来源：
CATALYSIS LETTERS | 2009年 / 128卷 / 3-4期
关键词：
Ionic liquid; Dimethyl carbonate; Methanol; Carbon dioxide; Propylene oxide; ETHYLENE-OXIDE; SUPERCRITICAL CO2; EPOXIDES; CATALYSTS; GLYCOLS; SELECTIVITY;
D O I：
10.1007/s10562-008-9773-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A basic ionic liquid, namely choline hydroxide, was prepared and supported on MgO to form Choline hydroxide/MgO material. The supported ionic liquid material was characterized by XRD, FT-IR and TG and used as a catalyst in one-pot synthesis of dimethyl carbonate from propylene oxide, methanol and carbon dioxide. A good catalytic performance was obtained with 98% conversion of epoxide and selectivity of above 90% to DMC + PC over the composite catalyst. However, the catalyst could be reused three times without a significant change in its catalytic activity.
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收藏
页码：459 / 464
页数：6
相关论文
共 13 条
[1]   Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides and methanol using heterogeneous Mg containing smectite catalysts: effect of reaction variables on activity and selectivity performance [J].
Bhanage, BM ;
Fujita, S ;
Ikushima, Y ;
Torii, K ;
Arai, M .
GREEN CHEMISTRY, 2003, 5 (01) :71-75
[2]   Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides, and methanol using heterogeneous basic metal oxide catalysts with high activity and selectivity [J].
Bhanage, BM ;
Fujita, S ;
Ikushima, Y ;
Arai, M .
APPLIED CATALYSIS A-GENERAL, 2001, 219 (1-2) :259-266
[3]   Synthesis of dimethyl carbonate (DMC) from CO2, ethylene oxide and methanol using heterogeneous anion exchange resins as catalysts [J].
Cao, Min ;
Meng, Yuezhong ;
Lu, Yixin .
REACTION KINETICS AND CATALYSIS LETTERS, 2006, 88 (02) :251-259
[4]   One-pot synthesis of dimethyl carbonate and glycols from supercritical CO2, ethylene oxide or propylene oxide, and methanol [J].
Chang, YH ;
Jiang, T ;
Han, BX ;
Liu, ZM ;
Wu, WZ ;
Gao, L ;
Li, JC ;
Gao, HX ;
Zhao, GY ;
Huang, J .
APPLIED CATALYSIS A-GENERAL, 2004, 263 (02) :179-186
[5]   One-pot synthesis of dimethyl carbonate catalyzed by [bmim]BF4/CH3ONa [J].
Chen Xiuzhi ;
Hu Changwen ;
Su Junhua ;
Yu Tao ;
Gao Zhiming .
CHINESE JOURNAL OF CATALYSIS, 2006, 27 (06) :485-488
[6]   One-pot synthesis of dimethyl carbonate using ethylene oxide, methanol, and carbon dioxide under supercritical conditions [J].
Cui, HY ;
Wang, T ;
Wang, FJ ;
Gu, CR ;
Wang, PL ;
Dai, YY .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (17) :3865-3870
[7]   Synthesis of dimethyl carbonate from CO2, methanol, and epoxides using Re (CO)5 Cl/K2 CO3 as catalyst system [J].
Jiang Jia-li ;
Hua Rui-mao .
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2007, 23 (03) :374-376
[8]   The double component catalyst for the direct synthesis of dimethyl carbonate from carbon dioxide, propylene oxide and methanol [J].
Jiang, Q ;
Yang, Y .
CATALYSIS LETTERS, 2004, 95 (3-4) :127-133
[9]   Synthesis of dimethyl carbonate from methanol, propylene oxide and carbon dioxide over KOH/4A molecular sieve catalyst [J].
Li, Y ;
Zhao, XQ ;
Wang, YJ .
APPLIED CATALYSIS A-GENERAL, 2005, 279 (1-2) :205-208
[10]   Organic carbonates [J].
Shaikh, AAG ;
Sivaram, S .
CHEMICAL REVIEWS, 1996, 96 (03) :951-976
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