Contrasting melting behavior of zinc stearate and zinc oleate

被引：30
作者：
Barman, S
Vasudevan, S [1 ]
机构：
[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 02期
关键词：
D O I：
10.1021/jp055814m
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of a double bond in the middle of an otherwise flexible hydrocarbon chain on the melting of such assemblies has been investigated by comparing the melting behavior of zinc stearate and zinc oleate. By monitoring features in the infrared spectra that are characteristic of the global conformation of the hydrocarbon chain, it is shown that the double bond effectively decouples the thermal evolution of conformational disorder in the chain segments oil either side of the double bond and the melting of each of these segments in the assembly occurs as independent events.
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页码：651 / 654
页数：4
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