Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes

被引：105

作者：

Isse, AA

Falciola, L

Mussini, PR

Gennaro, A

机构：

[1] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy

[2] Univ Milan, Dept Phys Chem & Electrochem, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 03期

关键词：

D O I：

10.1039/b513801a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon-halogen bond is concerted with the ET.

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收藏

页码：344 / 346

页数：3

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