Hofmeister series and specific interactions of charged headgroups with aqueous ions

被引：394

作者：

Vlachy, Nina ^{[1
]}

Jagoda-Cwiklik, Barbara ^{[2
,3
]}

Vacha, Robert ^{[2
,3
]}

Touraud, Didier ^{[1
]}

Jungwirth, Pavel ^{[2
,3
]}

Kunz, Werner ^{[1
]}

机构：

[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany

[2] Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic

[3] Ctr Biomol & Complex Mol Syst, Prague 16610 6, Czech Republic

来源：

ADVANCES IN COLLOID AND INTERFACE SCIENCE | 2009年 / 146卷 / 1-2期

关键词：

Hofmeister series; Specific-ion effects; Surfactant headgroups; Molecular dynamics; NUCLEAR-MAGNETIC-RESONANCE; ALKALI-METAL; COUNTERION SPECIFICITY; ELECTROMOTIVE-FORCE; MOLECULAR-DYNAMICS; SURFACTANT; BINDING; SALT; MICELLES; WATER;

D O I：

10.1016/j.cis.2008.09.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, we propose a Hofmeister-like ordering of charged headgroups. To this purpose we review various literature data and complete them with some new experimental and computational results on interactions of ions with alkyl sulfates and carboxylates. We further combine the proposed headgroup ordering with the law of matching water affinities in order to obtain a general description and predictions of ion-headgroup interactions. Examples from colloidal chemistry and from biological systems are provided to illustrate the power of this approach. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：42 / 47

页数：6

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