Conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by acidic ionic liquids in dimethyl sulfoxide

被引：55
作者：
Hu, Zhao
Liu, Bing [1 ]
Zhang, Zehui
Chen, Lianqing
机构：
[1] South Cent Univ Nationalities, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
来源：
INDUSTRIAL CROPS AND PRODUCTS | 2013年 / 50卷
基金：
中国国家自然科学基金;
关键词：
Carbohydrates; Carboxylic acid functionalized ionic liquids; 5-Hydroxymethylfurfural; Dehydration; Alkylation; EFFICIENT CONVERSION; LANTHANIDE(III) IONS; DEHYDRATION; FRUCTOSE; CHEMICALS; CELLULOSE; SOLVENT; SYSTEM; SUGARS;
D O I：
10.1016/j.indcrop.2013.07.014
中图分类号：
S2 [农业工程];
学科分类号：
0828 ;
摘要：
An efficient process was developed for the conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) using DMSO as the solvent and an acidic ionic liquid 1-carboxypropyl-3-methyl imidazolium chloride ([CMIm]Cl) as the catalyst. The effects of various reaction parameters on HMF yields were investigated. HMF yields of 95.7% and 88.4% were obtained from fructose and inulin when reactions were carried out 120 degrees C after 120 min and 180 min, respectively. The combination of ZrOCl2 and [CMIm]Cl resulted in a 50.6% yield of HMF from glucose. HMF could also be synthesized using other carbohydrates with moderate to high yields. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：264 / 269
页数：6
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