A rare example of a porous Ca-MOF for the controlled release of biologically active NO

被引：129

作者：

Miller, Stuart R. ^{[1
]}

Alvarez, Elsa ^{[1
]}

Fradcourt, Lucie ^{[1
]}

Devic, Thomas ^{[1
]}

Wuttke, Stefan ^{[1
,2
]}

Wheatley, Paul S. ^{[3
]}

Steunou, Nathalie ^{[1
]}

Bonhomme, Christian ^{[4
]}

Gervais, Christel ^{[4
]}

Laurencin, Danielle ^{[5
]}

Morris, Russell E. ^{[3
]}

Vimont, Alexandre ^{[2
]}

Daturi, Marco ^{[2
]}

Horcajada, Patricia ^{[1
]}

Serre, Christian ^{[1
]}

机构：

[1] Univ Versailles St Quentin En Yvelines, CNRS, Inst Lavoisier, UMR 8180, F-78035 Versailles, France

[2] Univ Caen, CNRS, ENSICAEN, Lab Catalyse & Spectrochim, F-14050 Caen, France

[3] Univ St Andrews, EaStChem Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[4] Univ Paris 06, Lab Chim Matiere Condensee Paris, UMR 7574, CNRS,Coll France, F-75231 Paris 05, France

[5] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, UMR 5253, CNRS,ENSCM,UM2,UM1,CC 1701, F-34095 Montpellier 5, France

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 71期

基金：

英国工程与自然科学研究理事会; 英国生物技术与生命科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; BUILDING-BLOCKS; CALCIUM; STORAGE; HYDROGEN; IONS; ADSORPTION; NETWORKS; DELIVERY;

D O I：

10.1039/c3cc41987h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 1D-microporous 3D calcium tetracarboxylate MOF has been solvothermally prepared and its structure solved from single crystal data. It exhibits coordinatively unsaturated Ca2+ Lewis acid sites able to trap and deliver nitric oxide at a biological level.

引用

页码：7773 / 7775

页数：3

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