Optical properties of Ag(tripod)X with tripod=1,1,1-tris(diphenylphosphinomethyl)ethane and X- = Cl- and I-:: Intraligand and ligand-to-ligand charge transfer

被引：28

作者：

Kunkely, H ^{[1
]}

Vogler, A ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 01期

关键词：

electronic spectra; luminescence; charge transfer; silver; phosphine complexes;

D O I：

10.1016/j.ica.2005.06.083

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes Ag-I(tripod)X with tripod = 1,1,1-tris(diphenylphosphinomethyl)ethane and X- = Cl- and I- are luminescent in solution at r.t. It is suggested that the emission is a phosphorescence which originates from a tripod intraligand state for X = Cl (lambda(max) = 464 nm) and a X- -> tripod ligand-to-ligand charge transfer state for X = I (lambda(max) = 482 nm). (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：388 / 390

页数：3

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