Fabrication of flexible conductive films derived from poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonic acid) (PEDOT:PSS) on the nonwoven fabrics substrate

In this research, conducting poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonic acid) (PEDOT:PSS) aqueous dispersion was synthesized at first via chemical oxidative polymerization and followed by mixing it with poly(styrene-r-butyl acrylate) P(St-BA) aqueous latex, creating a conductive material with outstanding stretchability. The elastic conductive composite were then film formed on the glass and poly(ethylene terephthalate) (PET) nonwoven fabric substrate by spin coating and dip coating, respectively. Composite films with various contents of PEDOT:PSS polymer (10-100 wt.%) had been prepared. From the conductivity measurements, the conductivity was still kept as high as 88 S cm(-1) even the PEDOT:PSS content was lowered to 10 wt.%. Furthermore, the elasticity of conductive films on the PET-onwoven fabric substrate was evaluated by the 180 degrees bending test repeating 100 times. With introducing soft P(St-BA) material in the PEDOT:PSS phase, the surface resistance increased merely 3-6 times after bending 100 times, while the surface resistance for pure PEDOT:PSS film could reach 18-20 times. (C) 2013 Elsevier B.V. All rights reserved.