Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane

被引：6
|
作者：
Spichal, Zdenek
Jancarik, Andrej
Mazal, Ctibor
Pinkas, Jiri
Pekarkova, Pavia
Necas, Marek [1 ]
机构：
[1] Masaryk Univ, Fac Sci, Dept Chem, CS-61137 Brno, Czech Republic
来源：
POLYHEDRON | 2013年 / 62卷
关键词：
Bicyclopentanes; Lanthanides; Coordination polymers; X-ray crystallography; COMPLEXES; DIOXIDE;
D O I：
10.1016/j.poly.2013.06.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1,3-bis(diphenylphosphoryl)bicyclo[1.1.1]pentane (1) with lanthanide nitrates provided a series of layered network coordination polymers Ln(1)(1.5)(NO3)(3) (Ln = Ce, Pr, Nd, Eu, Tb, Er, Yb, Lu). Crystal structures of all members of the series were determined by single crystal X-ray diffraction and were found isostructural. The compounds were studied by IR spectroscopy, luminescence spectroscopy, thermal analysis (TG/DSC) and powder X-ray diffraction (PXRD) techniques. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：83 / 88
页数：6
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