Complexation chemistry in liquid-liquid extraction of rhenium

被引：58

作者：

Srivastava, Rajiv Ranjan ^{[1
,2
]}

Lee, Jae-chun ^{[1
,2
]}

Kim, Min-seuk ^{[1
,2
]}

机构：

[1] Korea Univ Sci & Technol, Resources Recycling, Taejon 305350, South Korea

[2] Korea Inst Geosci & Mineral Resources KIGAM, Mineral Resources Res Div, Taejon 305350, South Korea

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 2015年 / 90卷 / 10期

关键词：

rhenium; solvation extraction; anion exchange extraction; synergistic extraction; H-bonding; DUST LEACHING SOLUTION; SULFURIC-ACID MEDIA; N-BUTYL PHOSPHATE; SOLVENT-EXTRACTION; TRIOCTYLPHOSPHINE OXIDE; METAL-IONS; MOLYBDENUM; THERMODYNAMICS; SEPARATION; BEHAVIOR;

D O I：

10.1002/jctb.4707

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

This review addresses the dearth of knowledge about the interaction of rhenium species with organic solvents during the liquid-liquid extraction of rhenium. To describe such interactions, the aqueous chemistry of rhenium in unlike media, the extraction mechanism and the salient role of thermodynamic properties are also discussed. Formation of a rhenium-complexed species inorganic phase and competition between the extracted species during extraction is described by inner and outer sphere coordination. Emergence of a stabilized complex in a hydrophobic environment is greatly affected by the interaction of electrostatic and/or H-bonding. The chemistry of liquid-liquid extraction of rhenium that can further assist future studies in this area is also relevant to other metal ion systems. (c) 2015 Society of Chemical Industry

引用

页码：1752 / 1764

页数：13

共 59 条

[1] Review of technologies for rhenium recovery from mineral raw materials in Kazakhstan [J].

Abisheva, Z. S. ;

Zagorodnyaya, A. N. ;

Bekturganov, N. S. .

HYDROMETALLURGY, 2011, 109 (1-2) :1-8

[2] Thermodynamics of extraction of MoO42- from aqueous sulfuric acid media with TBP dissolved in kerosene [J].

Alamdari, EK ;

Sadrnezhead, SK .

HYDROMETALLURGY, 2000, 55 (03) :327-341

[3] Extractive metallurgy of rhenium: a review [J].

Anderson, C. D. ;

Taylor, P. R. ;

Anderson, C. G. .

MINERALS & METALLURGICAL PROCESSING, 2013, 30 (01) :59-73

[4]

[Anonymous], 2011, Energy critical elements

[5] STRUCTURE AND REACTIVITY OF THE OXYANIONS OF TRANSITION METALS .8. ACIDITIES AND SPECTRA OF PROTONATED OXYANIONS [J].

BAILEY, N ;

CARRINGTON, A ;

LOTT, KAK ;

SYMONS, MCR .

JOURNAL OF THE CHEMICAL SOCIETY, 1960, (JAN) :290-297

[6] EXTRACTION OF HREO4, HCLO4 AND HAUCL4 BY TRIOCTYLPHOSPHINE OXIDE IN BENZENE, 1,3,5-TRIETHYLBENZENE AND CHLOROFORM [J].

BUCHER, JJ ;

ZIRIN, M ;

LAUGEN, RC ;

DIAMOND, RM .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (11) :3869-&

[7] EXTRACTION OF HAUCL4 AND HCLO4 BY TRIOCTYLPHOSPHINE OXIDE IN CCL4, ISOOCTANE AND CYCLOHEXANE [J].

BUCHER, JJ ;

DIAMOND, RM .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (11) :3531-&

[8]

Churchward P., 1963, report of investigations 6246

[9]

Churchward P., 1966, US Patent, Patent No. [3244475, 3,244,475]

[10] ON THE STRUCTURE OF THE RHENIDE ION [J].

COBBLE, JW .

JOURNAL OF PHYSICAL CHEMISTRY, 1957, 61 (06) :727-729

← 1 2 3 4 5 6 →