Cyclodextrin as a macrocyclic monomer:: Cationic ring-opening polymerization of O-permethylcyclodextrins

被引：0
|
作者：
Suzuki, M [1 ]
Numata, O [1 ]
Shimazaki, T [1 ]
机构：
[1] Tokyo Inst Technol, Ctr Macromol Sci, Grad Sch Sci & Engn & Int Res, Dept Organ & Polymer Mat, Tokyo 1528552, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2001年 / 22卷 / 16期
关键词：
D O I：
10.1002/1521-3927(20011101)22:16<1354::AID-MARC1354>3.0.CO;2-K
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
It has been disclosed for the first time that a cyclodextrin (CD) derivative is able to act as a microcyclic monomer for ring-opening polymerization to produce linear polyglucan. O-Permethylated alpha-, beta-, and gamma -CDs were found to be polymerizable with the aid of a cationic initiator, e.g., Et3O+PF6- in dichloromethane. Interestingly, the more strained monomer (alpha- > beta- > gamma -CD) was less reactive, which is ascribable to the characteristic shape of the CD molecule.
引用
收藏
页码：1354 / 1357
页数：4
相关论文
共 50 条
  • [41] Kinetics of cationic miniemulsion ring-opening polymerization for octamethylcyclotertrasiloxane
    Shen Junyi
    Shan Guorong
    ACTA POLYMERICA SINICA, 2008, (01) : 13 - 17
  • [42] CATIONIC RING-OPENING POLYMERIZATION OF LACTONES IN THE PRESENCE OF ALCOHOL
    OKAMOTO, Y
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1991, 42-3 : 117 - 133
  • [43] SOLVATION OF ONIUM IONS IN CATIONIC RING-OPENING POLYMERIZATION
    MATYJASZEWSKI, K
    MACROMOLECULES, 1988, 21 (02) : 519 - 520
  • [44] SYNTHESIS OF ORGANOFUNCTIONAL POLYSILOXANES BY CATIONIC RING-OPENING POLYMERIZATION
    YILGOR, I
    MCGRATH, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 114 - POLY
  • [45] Cationic ring-opening polymerization of N-phenylazetidine
    Oike, H
    Washizuka, M
    Tezuka, Y
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2000, 201 (14) : 1673 - 1678
  • [46] KINETICALLY CONTROLLED FORMATION OF MACROCYCLIC OLIGOMERS IN THE RING-OPENING POLYMERIZATION
    MATYJASZEWSKI, K
    ZIELINSKI, M
    KUBISA, P
    SLOMKOWSKI, S
    CHOJNOWSKI, J
    PENCZEK, S
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1980, 181 (07): : 1469 - 1482
  • [47] Ring-Opening Metathesis Polymerization of a Naturally Derived Macrocyclic Glycolipid
    Peng, Yifeng
    Decatur, John
    Meier, Michael A. R.
    Gross, Richard A.
    MACROMOLECULES, 2013, 46 (09) : 3293 - 3300
  • [48] Ring-opening polymerization of bisphenol-A type macrocyclic oligocarbonate
    Sugiyama, J
    Nagahata, R
    Goyal, M
    Takeuchi, K
    KOBUNSHI RONBUNSHU, 1997, 54 (10) : 749 - 753
  • [49] Synthesis, structure and ring-opening polymerization of phenolphthalein macrocyclic polyarylates
    Jiang, HY
    Qi, YH
    Chen, TL
    Bo, SQ
    Ding, MX
    Gao, LX
    Xu, JP
    He, TB
    Zhang, Y
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2000, 201 (17) : 2385 - 2393
  • [50] NEW ASPECTS OF CATIONIC POLYMERIZATION OF SPIROORTHOESTER - CATIONIC SINGLE RING-OPENING POLYMERIZATION AND EQUILIBRIUM POLYMERIZATION
    CHIKAOKA, S
    TAKATA, T
    ENDO, T
    MACROMOLECULES, 1991, 24 (25) : 6557 - 6562
12345