Pattern transition between periodic Liesegang pattern and crystal growth regime in reaction-diffusion systems

被引:51
作者
Lagzi, Istvan [1 ,2 ]
Ueyama, Daishin [3 ]
机构
[1] Eotvos Lorand Univ, Dept Meteorol, H-1117 Budapest, Hungary
[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[3] Meiji Univ, Dept Math, Kawasaki, Kanagawa 2148571, Japan
关键词
PRECIPITATION BANDS; MODEL; PARTICLE; GEL; SIMULATIONS; GRADIENTS; RINGS; WIDTH;
D O I
10.1016/j.cplett.2008.12.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The pattern transition between periodic precipitation pattern formation ( Liesegang phenomenon) and pure crystal growth regimes is investigated in silver nitrate and potassium dichromate system in mixed agarose-gelatin gel. Morphologically different patterns were found depending on the quality of the gel, and transition between these typical patterns can be controlled by the concentration of gelatin in mixed gel. Effect of temperature and hydrodynamic force on precipitation pattern structure was also investigated. (C) 2008 Elsevier B. V. All rights reserved.
引用
收藏
页码:188 / 192
页数:5
相关论文
共 42 条
[1]   Formation of Liesegang patterns:: Simulations using a kinetic Ising model [J].
Antal, T ;
Droz, M ;
Magnin, J ;
Pekalski, A ;
Rácz, Z .
JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (08) :3770-3775
[2]   Profiles of Co(NH3)62+ and Ni(NH3)62+ complexes in two-cation Liesegang systems [J].
Badr, Layla ;
Sultan, Rabih .
CHEMICAL PHYSICS LETTERS, 2008, 453 (1-3) :40-44
[3]   A MODEL OF PATTERN-FORMATION BY PRECIPITATION [J].
CHERNAVSKII, DS ;
POLEZHAEV, AA ;
MULLER, SC .
PHYSICA D, 1991, 54 (1-2) :160-170
[4]   MICROSCOPIC APPROACH TO THE FORMATION OF LIESEGANG PATTERNS [J].
CHOPARD, B ;
LUTHI, P ;
DROZ, M .
JOURNAL OF STATISTICAL PHYSICS, 1994, 76 (1-2) :661-677
[5]   REACTION-DIFFUSION CELLULAR-AUTOMATA MODEL FOR THE FORMATION OF LIESEGANG PATTERNS [J].
CHOPARD, B ;
LUTHI, P ;
DROZ, M .
PHYSICAL REVIEW LETTERS, 1994, 72 (09) :1384-1387
[6]   Liesegang patterns: Studies on the width law [J].
Droz, M ;
Magnin, J ;
Zrinyi, M .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (19) :9618-9622
[7]  
FEENEY R, 1983, J CHEM PHYS, V78, P1293, DOI 10.1063/1.444867
[8]  
George J, 2005, J MATER SCI, V40, P5557, DOI 10.1007/s10855-005-4550-4
[9]   Intermediate colloidal formation and the varying width of periodic precipitation bands in reaction-diffusion systems [J].
George, J ;
Varghese, G .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 282 (02) :397-402
[10]   Formation of periodic precipitation patterns: a moving boundary problem [J].
George, J ;
Varghese, G .
CHEMICAL PHYSICS LETTERS, 2002, 362 (1-2) :8-12