Carboxyl Modification of Sugarcane Bagasse Hemicelluloses With Succinic Anhydride in Aqueous Solution

被引:2
作者
Wang, Lijun [1 ]
Liu, Xinliang [1 ]
Weng, Mengling [2 ]
Wu, Fusheng [1 ]
Li, Zhoujun [1 ]
Wang, Shuangfei [1 ]
机构
[1] Guangxi Univ, Inst Light Ind & Foodstuff Engn, Nanning 530004, Peoples R China
[2] Guangxi Sugarcane Res Inst, Nanning 530007, Peoples R China
关键词
sugarcane bagasse; hemicelluloses; carboxyl modification; characterization; SINGLE METAL SOLUTIONS; MERCERIZED CELLULOSE; ADSORPTION; REMOVAL; ETHANOL;
D O I
10.1520/JTE20120228
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper, we describe the modification of sugarcane bagasse with succinic anhydride to introduce carboxylic functions to sugarcane bagasse. The properties of the sugarcane bagasse hemicelluloses change after carboxyl modification. The influences of the chemical reaction on the conditions, the chemical composition, and the thermal stability of the modified product are described. One gram of dried sugarcane bagasse was modified using 3.0 g succinic anhydride and 0.1 g N-bromination succinic imide with a reaction time of 6 h at 70 degrees C. The obtained materials were characterized via Fourier transform infrared spectroscopy, nuclear magnetic resonance, thermal analysis, and scanning electron microscopy.
引用
收藏
页码:517 / 524
页数:8
相关论文
共 26 条
[1]   Removal of nickel (II) ions from aqueous solutions by biosorption on sugarcane bagasse [J].
Aloma, I. ;
Martin-Lara, M. A. ;
Rodriguez, I. L. ;
Blazquez, G. ;
Calero, M. .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2012, 43 (02) :275-281
[2]   Adsorption of Cu(II), Cd(II) and Pb(II) from aqueous single metal solutions by succinylated twice-mercerized sugarcane bagasse functionalized with triethylenetetramine [J].
Alves Gurgel, Leandro Vinicius ;
Gil, Laurent Frederic .
WATER RESEARCH, 2009, 43 (18) :4479-4488
[3]   Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by succinylated mercerized cellulose modified with triethylenetetramine [J].
Alves Gurgel, Leandro Vinicius ;
Gil, Laurent Frederic .
CARBOHYDRATE POLYMERS, 2009, 77 (01) :142-149
[4]   Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith [J].
Amin, Nevine Kamal .
DESALINATION, 2008, 223 (1-3) :152-161
[5]   Sugarcane bagasse hemicellulose hydrolysate for ethanol production by acid recovery process [J].
Cheng, Ke-Ke ;
Cai, Bai-Yan ;
Zhang, Jian-An ;
Ling, Hong-Zhi ;
Zhou, Yu-He ;
Ge, Jing-Ping ;
Xu, Jing-Ming .
BIOCHEMICAL ENGINEERING JOURNAL, 2008, 38 (01) :105-109
[6]   Influence of pretreatment for deashing of sugarcane bagasse on pyrolysis products [J].
Das, P ;
Ganesh, A ;
Wangikar, P .
BIOMASS & BIOENERGY, 2004, 27 (05) :445-457
[7]   Production of bioethanol and other bio-based materials from sugarcane bagasse: Integration to conventional bioethanol production process [J].
Dias, Marina O. S. ;
Ensinas, Adriano V. ;
Nebra, Silvia A. ;
Maciel Filho, Rubens ;
Rossell, Carlos E. V. ;
Wolf Maciel, Maria Regina .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2009, 87 (9A) :1206-1216
[8]   Application of succinylated sugarcane bagasse as adsorbent to remove methylene blue and gentian violet from aqueous solutions - Kinetic and equilibrium studies [J].
Guimaraes Gusmao, Karla Aparecida ;
Alves Gurgel, Leandro Vinicius ;
Sacramento Melo, Tania Marcia ;
Gil, Laurent Frederic .
DYES AND PIGMENTS, 2012, 92 (03) :967-974
[9]   Removal of Ca(II) and Mg(II) from aqueous single metal solutions by mercerized cellulose and mercerized sugarcane bagasse grafted with EDTA dianhydride (EDTAD) [J].
Karnitz Junior, Osvaldo ;
Alves Gurgel, Leandro Vinicius ;
Gil, Laurent Frederic .
CARBOHYDRATE POLYMERS, 2010, 79 (01) :184-191
[10]   Adsorption of heavy metal ion from aqueous single metal solution by chemically modified sugarcane bagasse [J].
Karnitz, Osvaldo, Jr. ;
Alves Gurgel, Leandro Vinicius ;
Perin de Melo, Julio Cesar ;
Botaro, Vagner Roberto ;
Sacramento Melo, Tdnia Maircia ;
de Freitas Gil, Rossimiriam Pereira ;
Gil, Laurent Frederic .
BIORESOURCE TECHNOLOGY, 2007, 98 (06) :1291-1297