Chemical Bonding Characteristics of Lanthanide Complexes: A Case of Valence Study

被引：4

作者：

Zhang, Huan ^{[1
]}

Zhang, Xu ^{[1
]}

Ma, Junguo ^{[1
]}

机构：

[1] Shenyang Univ Technol, Sch Petrochem Engn, Liaoyang 111003, Peoples R China

来源：

ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5 | 2013年 / 634-638卷

关键词：

Lanthanides; Metal organic complex; Bond valence parameter; PARAMETERS;

D O I：

10.4028/www.scientific.net/AMR.634-638.3

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A number of newly Ln-N bond valence parameters were quantitatively estimated, which allowed us to obtain all Ln-N bond lengths with different coordination numbers in metal organic complexes. Twenty linear correlations among the mean bond valence parameters of Ln-O, Ln-N, Ln-S, Ln-Cl and Ln-C bonds of metal organic complexes have been well established and denoted by a set of linearity equations, which provides us a useful method to determine the bond valence parameters of other type La-atom bonds in coordination chemistry. The present work shows us a novel approach to deeply understand the chemical bonding characteristics between Ln and the ligands in various metal organic complexes.

引用

页码：3 / 6

页数：4

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