Classification of coordination polygons and polyhedra according to their mode of self-assembly. 2. Review of the literature

被引:277
作者
Swiegers, GF [1 ]
Malefetse, TJ [1 ]
机构
[1] CSIRO, Div Mol Sci, Clayton, Vic 3169, Australia
基金
新加坡国家研究基金会;
关键词
metallocycles; self-assembly; supramolecular chemistry;
D O I
10.1016/S0010-8545(01)00407-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Numerous molecular polygons and polyhedra, formed by metal-mediated self-assembly, have been described in the chemical literature in recent years. This work reviews such compounds in terms of the recently described 'assembly descriptor' classification which groups them according to similarity in the stoichiometry and building block topicity of their self-assembly. Relationships between different ensemble types and the application of the new system to the controlled, rational preparation of novel assemblies is emphasised. Published by Elsevier Science B.V.
引用
收藏
页码:91 / 121
页数:31
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