Thermal diffusivity and adsorption kinetics of silica-gel/water

被引:32
作者
Gurgel, JM
Andrade, LS
Grenier, P
Meunier, F
机构
[1] UFPB, LES, CT, DTM,CPGEM, BR-58059100 Joao Pessoa, Paraiba, Brazil
[2] CNRS, LIMSI, F-91403 Orsay, France
[3] Conservatoire Natl Arts & Metiers, IFFI, F-75141 Paris, France
来源
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY | 2001年 / 7卷 / 03期
关键词
silica-gel; adsorption; conductivity; mass diffusivity;
D O I
10.1023/A:1012732817374
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
There have been performed experimental measurements of effective thermal conductivity of silica-gel for a stagnant cylindrical fixed bed under transient and steady state conditions in the presence of dry air at different pressures and for different amounts of adsorbed water. The Bauer-Schlunder and Kunii-Smith models have been used to identify the thermal solid conductivity of silica gel pellets from measurements of the conductivity in an adsorbent bed. Sorption rates of water vapor in silica gel were measured using a single-step thermal method by monitoring the sample surface temperature by infrared detection. In order to obtain the mass diffusivity it is necessary to match the numerical solution of the mathematical model to the experimental data.
引用
收藏
页码:211 / 219
页数:9
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